{"created":"2023-07-27T06:50:17.970250+00:00","id":43025,"links":{},"metadata":{"_buckets":{"deposit":"0cdcdf32-61e5-418b-b02f-5fb3431d50a4"},"_deposit":{"created_by":18,"id":"43025","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"43025"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00043025","sets":["2812:2813:2824"]},"author_link":["69217","3942"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-05-25","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2007-2009","bibliographic_titles":[{"bibliographic_title":"平成21(2009)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2009 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では,様々な架橋基を持つ二核化配位子を含む(μ-η^2-η^2-peroxo)Cu(II)_2,bis(μ-oxo)Ni(III)_2および(μ1,2-peroxo)Fe(III)_2錯体の合成に成功した。その結果,銅錯体は様々なC-H結合エネルギーを持つ脂肪族化合物の酸化能を持つことを見出した。またニッケル錯体は架橋キシリル基の水酸化能を持つことが明らかとなった。さらに鉄錯体でも配位子に組込んだメチル基の水酸化および様々な外部基質の酸化反応に成功した。","subitem_description_type":"Abstract"},{"subitem_description":"(μ-η^2:η^2-Peroxo)dicopper(II), bis(μ-oxo)dinickel(III), and (μ-1,2-peroxo)Fe(III)_2 complexes having a variety of dinucleating ligands were prepared. The copper complexes are capable of initiating the oxidation of aliphatic C-H bonds having BDEs from ～74-～92 kcal mol^<-1>. The nickel complexes are also capable of hydroxylating the m-xylyl linker of the supporting ligands. Oxidation ability of the diiron complexes was also investigated.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:19350029, 研究期間(年度):2007-2009","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「酸素活性種を含む金属錯体の創製と反応場による機能制御」課題番号19350029\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-19350029/19350029seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00049374","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=20091390"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=20091390","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19350029/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19350029/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-19350029/19350029seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-19350029/19350029seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-11"}],"displaytype":"detail","filename":"SC-PR-SUZUKI-M-kaken 2011-5p.pdf","filesize":[{"value":"486.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-SUZUKI-M-kaken 2011-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/43025/files/SC-PR-SUZUKI-M-kaken 2011-5p.pdf"},"version_id":"7aecd230-c636-4c09-88f2-ad0c9f198814"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"酸素活性種を含む金属錯体の創製と反応場による機能制御","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"酸素活性種を含む金属錯体の創製と反応場による機能制御"},{"subitem_title":"Development of metal complexes having active oxygen species by controlling of reaction cavity","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2824"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-12-11"},"publish_date":"2017-12-11","publish_status":"0","recid":"43025","relation_version_is_last":true,"title":["酸素活性種を含む金属錯体の創製と反応場による機能制御"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:15:52.599395+00:00"}