{"created":"2023-07-27T06:50:18.105071+00:00","id":43028,"links":{},"metadata":{"_buckets":{"deposit":"ca7f5a90-54c3-4bd8-8533-8a603061567b"},"_deposit":{"created_by":18,"id":"43028","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"43028"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00043028","sets":["2812:2813:2834"]},"author_link":["69217","3942"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2000-03","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"16p.","bibliographicVolumeNumber":"1998-1999","bibliographic_titles":[{"bibliographic_title":"平成11(1999)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"1999 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では二核金属タンパクの機能モデルの構築を目的とし,酸素運搬体であるヘムエリトリンやヘモシアニンの機能モデルとして,二核鉄及び銅酸素錯体の設計・開発を行った。特に二核鉄錯体では,μ-peroxo錯体の熱的安定性と酸素親和性の制御,さらに銅錯体では単核superoxo銅およびμ-peroxo二核銅錯体の作り分けに成功した。\n鉄酸素錯体:様々な二核化配位子を用い二核cis-μ-1,2-peroxo鉄錯体の不可逆的酸化の防止を試みた。その結果今回得られた酸素錯体([Fe_2(Ph-bimp)((C_6H_5)_2CHCO_2)(O_2)]^<2+> Ph-bimp = 2,6-bis[bis{2-(1-methyl-4,5-diphenylimidazolyl)methyl}aminomethyl]-4-methylphenolate)では,40℃の高温でも可逆的酸素化が可能となった。結晶構造解析から二核化配位子(Ph-bimp)のフェニル基と架橋カルボン酸イオンのフェニル基が,酸素結合部位を囲む疎水的反応場を作り,これが酸素錯体の熱的安定性に大きく寄与していることが明らかとなった。また二核化配位子の架橋骨格の立体化学により酸素親和性を数万倍の範囲で制御可能であることを見い出した。高酸素親和性および低酸素親和性錯体のそれぞれの酸素化前後の錯体の結晶構造解析に成功し,高酸素親和性錯体では,酸素化前後で大きな構造変化がなく,低酸素親和性錯体では大きな構造変化があることが明らかとなった。\n銅酸素錯体:様々な置換基を持つ三脚型四座配位子((R_1R_2NCH_2CH_2)_3N:L)を用い銅(I)錯体([Cu(L)]^+)と酸素との反応性を調べた。その結果,置換基の立体的かさ高さにより単核superoxoおよび二核trans-μ-1,2-peroxo錯体の作り分けに成功し,構造および様々な分光学的性質を明らかにした。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:10640540, 研究期間(年度):1998-1999","subitem_description_type":"Other"},{"subitem_description":"出典：「機能化を目指した二核遷移金属錯体の分子設計」研究成果報告書　課題番号10640540\n  (KAKEN：科学研究費助成事業データベース（国立情報学研究所）)\n　　　本文データは著者版報告書より作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00049377","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学物質化学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=20091390"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=20091390","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10640540/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10640540/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-10640540/106405401999kenkyu_seika_hokoku_gaiyo/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-10640540/106405401999kenkyu_seika_hokoku_gaiyo/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-11"}],"displaytype":"detail","filename":"SC-PR-SUZUKI-M-kaken 2000-16p.pdf","filesize":[{"value":"804.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-SUZUKI-M-kaken 2000-16p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/43028/files/SC-PR-SUZUKI-M-kaken 2000-16p.pdf"},"version_id":"023cad8e-4f5e-4089-8444-056a90ee05ba"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"機能化を目指した二核遷移金属錯体の分子設計","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"機能化を目指した二核遷移金属錯体の分子設計"},{"subitem_title":"Functionalization of Dimetal Complexes by Ligand Design","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2834"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-12-11"},"publish_date":"2017-12-11","publish_status":"0","recid":"43028","relation_version_is_last":true,"title":["機能化を目指した二核遷移金属錯体の分子設計"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T14:48:35.836838+00:00"}