{"created":"2023-07-27T06:50:44.541095+00:00","id":43775,"links":{},"metadata":{"_buckets":{"deposit":"0e777a9a-cb4f-415a-b73d-f561fb175915"},"_deposit":{"created_by":18,"id":"43775","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"43775"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00043775","sets":["934:935:937"]},"author_link":["145","71991","73300","73301"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-09","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"1130","bibliographicPageStart":"1123","bibliographicVolumeNumber":"242","bibliographic_titles":[{"bibliographic_title":"Journal of Molecular Liquids"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"長谷川, 浩"}],"nameIdentifiers":[{},{},{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The complexation of SrII and geochemically-related elements (MgII, CaII, BaII, and YIII) with biodegradable aminopolycarboxylate chelators (DL-2-(2-carboxymethyl)nitrilotriacetic acid (GLDA) and 3-hydroxy-2,2′-iminodisuccinic acid (HIDS)) was evaluated with the objective of using in the chemical-induced washing remediation of radioactive solid waste. The stability constants (log10KML) for metal-chelator (ML) complexes between M (MgII, CaII, SrII, BaII, or YIII) and L (GLDA or HIDS) in the aqueous matrix was derived from experimental potentiometric data (M:L = 1:1; ionic strength, I = 0.10 mol·dm− 3; T = 25 ± 0.1 °C). The formation of ML2 − species was dominant in the systems with MgII, CaII, SrII, or BaII, while M(OH)L2 − or M(OH)2L3 − was the major species with YIII. The stability of YIII-L complexes was higher than that of MgII, CaII, SrII, or BaII, while the order for complexation strength of GLDA and HIDS was not similar with divalent ions: M-GLDA (log10KMg-L < log10KCa-L > log10KSr-L > log10KBa-L), M-HIDS (log10KMg-L > log10KCa-L > log10KSr-L > log10KBa-L). The conditional stability constants for the ML systems was also derived in terms of pH (2 to 12), and compared with that of EDTA and EDDS. The data trend indicated that the overall stability of the complexes of MgII, CaII, SrII, BaII, or YIII with GLDA or HIDS was better than the biodegradable chelator EDDS, which was frequently recommended as the alternative to EDTA. © 2017 Elsevier B.V.","subitem_description_type":"Abstract"}]},"item_4_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Embargo Period 12 months","subitem_description_type":"Other"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系   ","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050117","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier B.V."}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.molliq.2017.07.126","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.elsevier.com/locate/issn/01677322"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.elsevier.com/locate/issn/01677322","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2017 Elsevier B.V."}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA10636062","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0167-7322","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Begun, Zinnat A."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rahman, Ismail M.M."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hasegawa, Hiroshi"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-09-02"}],"displaytype":"detail","filename":"SC-PR-HASEGAWA-H-1123.pdf","filesize":[{"value":"599.3 kB"}],"format":"application/pdf","licensetype":"license_6","mimetype":"application/pdf","url":{"label":"SC-PR-HASEGAWA-H-1123.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/43775/files/SC-PR-HASEGAWA-H-1123.pdf"},"version_id":"8146f38e-a066-4777-b11e-1bd843338f5c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Complexation behavior of SrII and geochemically-related elements (MgII, CaII, BaII, and YIII) with biodegradable aminopolycarboxylate chelators (GLDA and HIDS)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Complexation behavior of SrII and geochemically-related elements (MgII, CaII, BaII, and YIII) with biodegradable aminopolycarboxylate chelators (GLDA and HIDS)"}]},"item_type_id":"4","owner":"18","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-02-15"},"publish_date":"2018-02-15","publish_status":"0","recid":"43775","relation_version_is_last":true,"title":["Complexation behavior of SrII and geochemically-related elements (MgII, CaII, BaII, and YIII) with biodegradable aminopolycarboxylate chelators (GLDA and HIDS)"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T17:41:11.574437+00:00"}