{"created":"2023-07-27T06:51:09.882117+00:00","id":44458,"links":{},"metadata":{"_buckets":{"deposit":"2aceb37f-f1cd-49c1-b51b-a66837b91f49"},"_deposit":{"created_by":18,"id":"44458","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44458"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044458","sets":["2812:2813:2823"]},"author_link":["76135","469"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-05-23","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2008-2010","bibliographic_titles":[{"bibliographic_title":"平成22(2010)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2010 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"フッ素アニオンにより活性化された有機ケイ素化合物を一電子酸化剤であるCe(IV)と反応させることで、種々のタイプの炭素ラジカルを発生させることが出来るものと考え、研究を行った。現在のところ、この方法によるラジカルの発生を確認するには至っていないが、本研究の過程で、触媒量のCe(IV)あるいはCe(III)を用いた水系反応によって酸化的なラジカル炭素-炭素結合形成が可能であることを見出すことが出来た。","subitem_description_type":"Abstract"},{"subitem_description":"Ce(IV)-mediated radical generation from organosilicon compounds activated by fluoride ion was studied. Although the generation of radical by this method has not been obsereved to date, we observed the C-C bond formation reactions with catalytic amount of Ce(IV) or Ce(III) in aqueous media in the course of this study.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"出典：研究課題「Ce(IV)とフッ素アニオンを用いる有機ケイ素化合物からの新規ラジカル発生法の開発」課題番号20590003\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20590003/20590003seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学学際科学実験センター機器分析研究施設","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050800","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40277265"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40277265","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20590003/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20590003/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20590003/20590003seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20590003/20590003seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-21"}],"displaytype":"detail","filename":"AD-PR-UCHIYAMA-M-kaken 2011-4p.pdf","filesize":[{"value":"208.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"AD-PR-UCHIYAMA-M-kaken 2011-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44458/files/AD-PR-UCHIYAMA-M-kaken 2011-4p.pdf"},"version_id":"774d301c-03de-4543-9d4f-4cd0cace2f8d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"Ce(IV)とフッ素アニオンを用いる有機ケイ素化合物からの新規ラジカル発生法の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ce(IV)とフッ素アニオンを用いる有機ケイ素化合物からの新規ラジカル発生法の開発"},{"subitem_title":"A study on Ce(IV)-mediated radical generation from organosilicon compounds activated by fluoride ion","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2823"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-21"},"publish_date":"2018-05-21","publish_status":"0","recid":"44458","relation_version_is_last":true,"title":["Ce(IV)とフッ素アニオンを用いる有機ケイ素化合物からの新規ラジカル発生法の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:17:44.265075+00:00"}