{"created":"2023-07-27T06:51:11.967537+00:00","id":44526,"links":{},"metadata":{"_buckets":{"deposit":"0971baa9-bd49-43a6-ae9d-db28bcf3f262"},"_deposit":{"created_by":18,"id":"44526","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44526"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044526","sets":["2812:2813:2818"]},"author_link":["76422","76421"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-06-09","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2014-04-01 - 2016-03-31","bibliographic_titles":[{"bibliographic_title":"平成27(2015)年度 科学研究費補助金 挑戦的萌芽研究 研究成果報告書"},{"bibliographic_title":"2015 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"不安定な活性種であるカルボカチオンを用いた不斉誘起は挑戦的かつ魅力的な研究課題である。申請者らは、プロキラルなカルボカチオンに対して、光学活性な不斉エーテルが面選択的に配位すれば、求核剤との反応において立体選択性の発現が可能であると考えた。その結果、本研究において、反応に必要なカルボカチオンを発生可能な各種反応剤の開発に成功し、さらに、不斉エーテル存在下、フェネチルカチオン種のFriedel-Crafts反応において、選択性は十分ではないが、不斉が誘起されることを見出した。","subitem_description_type":"Abstract"},{"subitem_description":"Asymmetric induction utilizing highly reactive carbocations is an attractive and challenging theme. We hypothesized that if an optically active asymmetric ether coordinates to a prochiral carbocation in a face-selective manner, stereoselectivity can be achieved in alkylation of nucleophiles. As a result, we succeeded in development of various reagents that enable to generate carbocationic species available for the study of asymmetric induction. In addition, in a Friedel-Crafts reaction using phenethylcationic species in the presence of an asymmetric ether, we observed asymmetric induction even though the selectivity was insufficient.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:26670001, 研究期間(年度):2014-04-01 - 2016-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「カルボカチオンを活性種とする不斉誘起反応の開発」課題番号26670001\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26670001/26670001seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050867","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80453835"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80453835","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26670001/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26670001/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26670001/26670001seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26670001/26670001seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-31"}],"displaytype":"detail","filename":"PH-PR-KUNISHIMA-M-kaken 2016-4p.pdf","filesize":[{"value":"345.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-KUNISHIMA-M-kaken 2016-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44526/files/PH-PR-KUNISHIMA-M-kaken 2016-4p.pdf"},"version_id":"65f4e4fe-e511-43ef-8578-51d7b298c2a8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"カルボカチオンを活性種とする不斉誘起反応の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"カルボカチオンを活性種とする不斉誘起反応の開発"},{"subitem_title":"Asymmetric induction by using carbocations as a reactive species","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2818"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-31"},"publish_date":"2018-05-31","publish_status":"0","recid":"44526","relation_version_is_last":true,"title":["カルボカチオンを活性種とする不斉誘起反応の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T10:56:42.345908+00:00"}