{"created":"2023-07-27T06:51:12.148083+00:00","id":44530,"links":{},"metadata":{"_buckets":{"deposit":"0afe2fa2-645c-4953-b8b6-d5c4bdd90b57"},"_deposit":{"created_by":18,"id":"44530","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44530"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044530","sets":["2812:2813:2821"]},"author_link":["76425","76426"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-05-24","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2011-2012","bibliographic_titles":[{"bibliographic_title":"平成24(2012)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2012 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"ベンジル化剤DMT-BMに対して種々の構造変換を行った結果、反応性・溶解性が向上し、室温、2時間で反応が進行する優れたベンジル化剤が開発できた。反応条件については、共存する塩基と溶媒の組み合わせが重要であることがわかった。これにより、ほぼ中性条件で反応を行うことができ、酸性条件や塩基性条件に対して脆弱な官能基を有する基質への適用範囲の拡大が可能となった。また、この反応剤を基盤として、種々の新規反応剤や新規反応を開発した。","subitem_description_type":"Abstract"},{"subitem_description":"A New benzylating reagent, which can make alcohols benzylated at room temperature within 2 hours, was developed. The specified combinations of the solvents and the coexisting bases are effective for the improvement of the yields of the benzyl ethers. These conditions can be applied to alcohols possessing highly functionalized compounds. Based on these results, we developed another new reagents and a reaction.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:23790009, 研究期間(年度):2011-2012","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「温和な条件で進行するベンジル化剤DMT-BMの開発」課題番号23790009\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23790009/23790009seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050871","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40583232"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40583232","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23790009/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23790009/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23790009/23790009seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23790009/23790009seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-31"}],"displaytype":"detail","filename":"PH-PR-YAMADA-K-kaken 2013-4p.pdf","filesize":[{"value":"358.7 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-YAMADA-K-kaken 2013-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44530/files/PH-PR-YAMADA-K-kaken 2013-4p.pdf"},"version_id":"28f3ecd6-109f-4b05-bd10-6d0560894115"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"温和な条件で進行するベンジル化剤DMT-BMの開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"温和な条件で進行するベンジル化剤DMT-BMの開発"},{"subitem_title":"Development of a new benzylating reagent, DMT-BM","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2821"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-31"},"publish_date":"2018-05-31","publish_status":"0","recid":"44530","relation_version_is_last":true,"title":["温和な条件で進行するベンジル化剤DMT-BMの開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:41:28.816034+00:00"}