{"created":"2023-07-27T06:51:12.192723+00:00","id":44531,"links":{},"metadata":{"_buckets":{"deposit":"37bb206e-bc5a-4e69-a528-bc84f18c8ea3"},"_deposit":{"created_by":18,"id":"44531","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44531"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044531","sets":["2812:2813:2816"]},"author_link":["76429","76454"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05-26","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2015-04-01 - 2018-03-31","bibliographic_titles":[{"bibliographic_title":"平成29(2017)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2017 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"３－エトキシシクロブタノンをルイス酸を用いて活性化して生ずる１，４－二極性活性種とアゾベンゼン、キノリン、イソキノリン、イナミド、ニトロソベンゼン、反応性の高いアルキン類との反応によって対応する6員環化合物が得られることを見出した。また、3－フェニルシクロブタノンをルイス酸で活性化して生ずる活性種は芳香族化合物と反応し、対応するFriedel-Crafts成績体が得られることを見出した。また、1，4－ケトアルデヒドとトシルヒドラジンからなる中間体から各種求核剤とルイス酸を用いることによってヒドロピリダジン誘導体を合成できることを見出した。","subitem_description_type":"Abstract"},{"subitem_description":"1,4-Zwitterionic intermediates which were generated by activation of 3-ethoxycyclobutanones with an appropriate Lewis acid reacted with azobenzenes, quinolines, isoquinolines, ynamides, nitrosobenzenes, and reactive alkynes gave the corresponding 6-membered cyclic compounds by formal [4+2] cycloaddition reactions. A zwitterionic intermediate generated from 3-phenylcyclobutanones reacted aromatics to afford Friedel-Crafts adducts. Also, an adduct between 1,4-ketoaldehyde and tosylhydrazine rected with nucleophiles under activation with a Lewis acid to give dihydropyridazines.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:15K07855, 研究期間(年度):2015-04-01 - 2018-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「シクロブタノンを活用する環化付加反応の新展開」課題番号15K07855\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K07855/15K07855seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050872","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=50328580"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=50328580","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K07855/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K07855/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K07855/15K07855seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K07855/15K07855seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-12"}],"displaytype":"detail","filename":"PH-PR-MATSUO-J-kaken 2018-5p.pdf","filesize":[{"value":"294.1 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-MATSUO-J-kaken 2018-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44531/files/PH-PR-MATSUO-J-kaken 2018-5p.pdf"},"version_id":"81a6f8cb-5537-444e-a4da-73733883c7b6"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"シクロブタノンを活用する環化付加反応の新展開","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"シクロブタノンを活用する環化付加反応の新展開"},{"subitem_title":"New development of cycloaddition reactions using cyclobutanones","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2816"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-04-12"},"publish_date":"2019-04-12","publish_status":"0","recid":"44531","relation_version_is_last":true,"title":["シクロブタノンを活用する環化付加反応の新展開"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:01:26.490288+00:00"}