{"created":"2023-07-27T06:51:12.326089+00:00","id":44534,"links":{},"metadata":{"_buckets":{"deposit":"3b4a56de-f509-441e-a05e-570b9bd9b30c"},"_deposit":{"created_by":18,"id":"44534","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44534"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044534","sets":["2812:2813:2825"]},"author_link":["76429","76454"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-04-01","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2007-2008","bibliographic_titles":[{"bibliographic_title":"平成20(2008)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2008 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"ラクタム、3-アルキルインドール、および1,3-ジケトンなどを酸化剤N-tert-butylbenzenesulfinimidoyl chloride (1)によって活性化し、中間体を単離することなくマロン酸エステルなど炭素求核剤を加えることによって、ラクタムの窒素原子のα位、インドール3位のアルキル基上およびカルボニル基のβ位にワンポットで直接炭素-炭素結合を導入できることを明らかにした。つまり、著者らは様々な含窒素化合物を酸化剤1によって酸化し、通常調製困難な中間体を簡便に生成させ、これを単離することなく炭素求核剤と反応させて炭素-炭素結合を形成させる手法を開発した。この手法は、一般に官能基化が困難な位置へ直接炭素-炭素結合を導入できる点が特徴である。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:19790012, 研究期間(年度):2007-2008","subitem_description_type":"Other"},{"subitem_description":"出典：「硫黄-窒素結合の特性を活用する実用的合成反応の開発」研究成果報告書　課題番号19790012\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-19790012/19790012seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050875","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=50328580"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=50328580","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19790012/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19790012/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-19790012/19790012seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-19790012/19790012seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-31"}],"displaytype":"detail","filename":"PH-PR-MATSUO-J-kaken 2009-4p.pdf","filesize":[{"value":"42.1 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-MATSUO-J-kaken 2009-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44534/files/PH-PR-MATSUO-J-kaken 2009-4p.pdf"},"version_id":"5120d727-10c7-4703-9c77-865637f2e4bc"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"硫黄-窒素結合の特性を活用する実用的合成反応の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"硫黄-窒素結合の特性を活用する実用的合成反応の開発"},{"subitem_title":"Development of practical organic reactions by utilizing characteristic feature of sulfur-nitrogen bond","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2825"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-31"},"publish_date":"2018-05-31","publish_status":"0","recid":"44534","relation_version_is_last":true,"title":["硫黄-窒素結合の特性を活用する実用的合成反応の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T14:14:59.023730+00:00"}