{"created":"2023-07-27T06:51:12.601644+00:00","id":44540,"links":{},"metadata":{"_buckets":{"deposit":"2d8d7b75-c482-4165-97bb-ed73af7b9e44"},"_deposit":{"created_by":18,"id":"44540","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44540"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044540","sets":["2812:2813:2821"]},"author_link":["26926","1882"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-04-19","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2011-2012","bibliographic_titles":[{"bibliographic_title":"平成24(2012)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2012 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"フタロシアニン鉄と分子状酸素を活用することによって、以下の三つの新しい反応を開発した:\n(1)ヒドラジン化合物からの新規ラジカル発生法とアルケンへの付加反応、\n(2)水素化ホウ素ナトリウムを用いる酸化還元水和反応を利用したアルケンからの直接的な1,4-ジオールの合成、\n(3)酸素を酸化剤とする酸化還元的エステル化反応。また、本研究過程で簡便なアルケンの酸化的ニトロ化反応を開発することができた。","subitem_description_type":"Abstract"},{"subitem_description":"Three novel reactions using iron phthalocyanine and molecular oxygen have been developed:\n(1) a new method for generation of radicals from hydrazine compounds and addition reactions of resultant radicals to alkenes\n(2) synthesis of 1,4-diols from simple alkenes by redox hydration using sodium borohydride\n(3) oxidation-reduction esterification using oxygen as an oxidant. In addition, mild oxynitration reactions of alkenes have been found in the courseof these studies.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:23790008, 研究期間(年度):2011-2012","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「フタロシアニン鉄と分子状酸素を活用する新規反応の開発研究」課題番号23790008\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23790008/23790008seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050881","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=60444204"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=60444204","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23790008/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23790008/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23790008/23790008seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23790008/23790008seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-31"}],"displaytype":"detail","filename":"PH-PR-TANIGUCHI-T-kaken 2013-5p.pdf","filesize":[{"value":"277.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-TANIGUCHI-T-kaken 2013-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44540/files/PH-PR-TANIGUCHI-T-kaken 2013-5p.pdf"},"version_id":"5f0d3def-596b-4391-9db2-cbfdb0780f13"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"フタロシアニン鉄と分子状酸素を活用する新規反応の開発研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フタロシアニン鉄と分子状酸素を活用する新規反応の開発研究"},{"subitem_title":"Development of new reactions using phthalocyanine and molecular oxygen","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2821"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-31"},"publish_date":"2018-05-31","publish_status":"0","recid":"44540","relation_version_is_last":true,"title":["フタロシアニン鉄と分子状酸素を活用する新規反応の開発研究"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:41:25.940639+00:00"}