{"created":"2023-07-27T06:51:12.646887+00:00","id":44541,"links":{},"metadata":{"_buckets":{"deposit":"6132148c-6f22-4cb6-8a11-de56d22b2302"},"_deposit":{"created_by":18,"id":"44541","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"44541"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00044541","sets":["2812:2813:2823"]},"author_link":["26926","1882"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-05-10","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2009-2010","bibliographic_titles":[{"bibliographic_title":"平成22(2010)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2010 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"カスケード型溝呂木-ヘック環化反応を用いてインデノテトラヒドロピリジン骨格の簡便な合成法を見出し、ハオウアミンAの形式合成を達成することができた。一方、プメラー型環化反応を用いたハオウアミンBの骨格合成は困難であることが明らかとなったが、本合成研究をきっかけとして、鉄触媒を用いるヒドラジン化合物からの新規ラジカル発生法やアルケンのニトロ化反応等の有用な反応を見出すことができた。","subitem_description_type":"Abstract"},{"subitem_description":"Formal synthesis of haouamine A has been achieved using cascade Mizoroki-Heck cyclization to give an indenotetrahydropyridine core. On the other hand, synthesis of a core of haouamine B using Pummerer-type cyclizations was difficult. However, this synthetic study gave us an opportunity to develop a new methodology such as iron-catalyzed radical reactions using hydrazine compounds and nitration reactions of alkenes.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"出典：研究課題「カスケード環化反応を基盤とする抗腫瘍性アルカロイドHaouamine類の合成研究」課題番号21790011\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21790011/21790011seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00050882","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=60444204"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=60444204","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21790011/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21790011/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21790011/21790011seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21790011/21790011seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-31"}],"displaytype":"detail","filename":"PH-PR-TANIGUCHI-T-kaken 2011-4p.pdf","filesize":[{"value":"188.3 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-TANIGUCHI-T-kaken 2011-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/44541/files/PH-PR-TANIGUCHI-T-kaken 2011-4p.pdf"},"version_id":"4db5193d-b1ef-408f-a8fc-a02dc77c63c8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"カスケード環化反応を基盤とする抗腫瘍性アルカロイドHaouamine類の合成研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"カスケード環化反応を基盤とする抗腫瘍性アルカロイドHaouamine類の合成研究"},{"subitem_title":"Synthetic Study of Antitumor Alkaloids Haouamines Using a Cascade Cyclization","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2823"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-31"},"publish_date":"2018-05-31","publish_status":"0","recid":"44541","relation_version_is_last":true,"title":["カスケード環化反応を基盤とする抗腫瘍性アルカロイドHaouamine類の合成研究"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:17:38.676796+00:00"}