{"created":"2023-07-27T06:51:47.593698+00:00","id":45355,"links":{},"metadata":{"_buckets":{"deposit":"5a73e71a-708e-4019-bcd7-8444aa095073"},"_deposit":{"created_by":18,"id":"45355","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"45355"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00045355","sets":["2812:2813:2817"]},"author_link":["78865","2671"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-05-31","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2014-04-01 - 2017-03-31","bibliographic_titles":[{"bibliographic_title":"平成28(2016)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2016 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"金属から電子を受容するZ型配位子が、金属錯体或いはその触媒反応へもたらす影響については、ほとんど報告例がなく知られていない。そこで、新規Z型配位子含有金錯体の合成および触媒反応への応用を試みた。その結果、３種の錯体の合成に成功し、錯体がカチオン性の状態では、金とZ型配位子間の相互作用が減弱すること、Z型配位子側に電子求引性基を導入するとη２型のZ-ligand effectが得られることを見出した。また触媒反応では、通常合成が艱難な7員環構築を含む2種の反応が進行することも明らかにした。","subitem_description_type":"Abstract"},{"subitem_description":"The Au complexes featuring a Z-type ligand (boron atom) as a σ-acceptor were developed for elucidating the effect of electron withdrawing on catalytic reactions. An cyclization in the presence of either [Au→B]+ or [Au]+ showed that [Au→B]+ promotes the reactivity, which enabled the effective construction of not only five- and six-membered rings, but also seven-membered rings.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:26460004, 研究期間(年度):2014-04-01 - 2017-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「Z型配位子を有するカチオン性金属錯体の合成とその応用研究」研究成果報告書　課題番号26460004\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26460004/26460004seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00051692","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80506816"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80506816","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26460004/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26460004/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26460004/26460004seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26460004/26460004seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-07-19"}],"displaytype":"detail","filename":"PH-PR-INAGAKI-F-kaken 2017-4p.pdf","filesize":[{"value":"212.2 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-INAGAKI-F-kaken 2017-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/45355/files/PH-PR-INAGAKI-F-kaken 2017-4p.pdf"},"version_id":"9c0e2308-87c4-4dd0-9b4e-4cfd3335f498"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"Z型配位子を有するカチオン性金属錯体の合成とその応用研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Z型配位子を有するカチオン性金属錯体の合成とその応用研究"},{"subitem_title":"Syntheses of Cationic Metal Complexes with Z-Ligand and Its Application","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2817"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-07-19"},"publish_date":"2018-07-19","publish_status":"0","recid":"45355","relation_version_is_last":true,"title":["Z型配位子を有するカチオン性金属錯体の合成とその応用研究"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T11:25:50.111702+00:00"}