{"created":"2023-07-27T06:51:47.637450+00:00","id":45356,"links":{},"metadata":{"_buckets":{"deposit":"57f0b9a9-e43a-4f88-a21c-f2ac9b3565d6"},"_deposit":{"created_by":18,"id":"45356","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"45356"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00045356","sets":["2812:2813:2820"]},"author_link":["78865","2671"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-05-27","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2012-04-01 - 2014-03-31","bibliographic_titles":[{"bibliographic_title":"平成25(2013)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2013 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1,これまでに簡便に合成可能であることを見出している中員環(8,9員環)トリエンの環上エキソジメチレンと種々の電子求引性基を有する三重結合成分とのDiels-Alder反応が進行することを見出し,ビシクロ[6.4.0],[7.4.0]誘導体が収率よく得られることを明らかにした.\n2,アルケン-アレニルシクロプロパンをロジウム触媒と処理したところ,これまでにない反応形式で環化が進行し,ビシクロ[4.3.0]誘導体が高ジアステレオ選択的に得られた.\n3,アレン-アレニルシクロプロパンを用いた新規[5+2-2]型環化付加反応を見出した.","subitem_description_type":"Abstract"},{"subitem_description":"We found that 1) Diels-Alder reaction of dienophile and exo-dimethylene derived from the cycloisomerization of bisallene provided the bicyclo[[m.4.0] derivatives (m=6,7), 2) Rh(I)-catalyzed cycloisomerization of alkene-substituted allenylcyclopropanes gave bicyclo[4.3.0]nonadienes stereoselectively, and 3) Rh(I)-catalyzed intramolecular [5+2-2] cycloadditions of allene-allenylcyclopropane formed the bicycle[5.3.0] derivatives.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:24790009, 研究期間(年度):2012-04-01 - 2014-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「多重結合成分を利用した新規双環性化合物構築法の開発」課題番号24790009\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24790009/24790009seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00051693","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80506816"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80506816","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24790009/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24790009/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24790009/24790009seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24790009/24790009seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-07-19"}],"displaytype":"detail","filename":"PH-PR-INAGAKI-F-kaken 2014-4p.pdf","filesize":[{"value":"469.6 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-INAGAKI-F-kaken 2014-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/45356/files/PH-PR-INAGAKI-F-kaken 2014-4p.pdf"},"version_id":"2b899595-6092-45ca-a624-0a48b7587334"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"多重結合成分を利用した新規双環性化合物構築法の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"多重結合成分を利用した新規双環性化合物構築法の開発"},{"subitem_title":"New method for the construction of bicyclic products by using multiple bonds","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2820"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-07-19"},"publish_date":"2018-07-19","publish_status":"0","recid":"45356","relation_version_is_last":true,"title":["多重結合成分を利用した新規双環性化合物構築法の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T09:18:25.604674+00:00"}