{"created":"2023-07-27T06:51:56.246108+00:00","id":45570,"links":{},"metadata":{"_buckets":{"deposit":"ab02907e-d686-4d0e-8659-ed0ed29f0edb"},"_deposit":{"created_by":18,"id":"45570","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"45570"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00045570","sets":["2812:2813:2823"]},"author_link":["79108","3945"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-05-09","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2008-2010","bibliographic_titles":[{"bibliographic_title":"平成22(2010)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2010 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"マイクロ波照射場で,ピコ秒の時間分解能で蛍光寿命を測定できる体系を組上げた。この装置を用いて,蛍光プローブ分子C153の回転運動に及ぼすマイクロ波照射の影響を検討した。プローブ分子の回転速度の温度依存性を検討し,それらの活性化エネルギーを求めた。回転速度の活性化エネルギーは,マイクロ波照射場では小さくなることが分かった。つまり,マイクロ波照射場では,プローブ分子の回転が容易であることがわかった。","subitem_description_type":"Abstract"},{"subitem_description":"An experimental apparatus that can measure fluorescence lifetime with picoseond time-resolution under microwave irradiation conditions was build up. Using the apparatus the effect of microwave irradiation on the rotational motion of a probe molecule C153 was investigated. The activation energy for the rotational motion was determined by measuring the temperature dependence of the rotational rate constants. It is found that the activation energy was reduced under the microwave irradiation conditions by comparing with that measured under conventional heating conditions. Therefore it may be concluded that, under the microwave irradiation conditions, the dipole molecule can rotate easily.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:20560712, 研究期間(年度):2008-2010","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「ナノ,ピコ秒時間分解分光法を用いたマイクロ波による反応促進機構の解明」課題番号20560712\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20560712/20560712seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00051907","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学理工研究域生命理工学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=00216714"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=00216714","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20560712/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20560712/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20560712/20560712seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20560712/20560712seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-17"}],"displaytype":"detail","filename":"SC-PR-TAKAHASHI-K-kaken 2011-6p.pdf","filesize":[{"value":"348.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-TAKAHASHI-K-kaken 2011-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/45570/files/SC-PR-TAKAHASHI-K-kaken 2011-6p.pdf"},"version_id":"3cf625b6-4350-482c-9d60-7f5f6c33e7ff"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"ナノ,ピコ秒時間分解分光法を用いたマイクロ波による反応促進機構の解明","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ナノ,ピコ秒時間分解分光法を用いたマイクロ波による反応促進機構の解明"},{"subitem_title":"Study on the mechanism of reaction rate enhancement by microwave irradiation using nano- and pico-second time resolved spectroscopy","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2823"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-08-17"},"publish_date":"2018-08-17","publish_status":"0","recid":"45570","relation_version_is_last":true,"title":["ナノ,ピコ秒時間分解分光法を用いたマイクロ波による反応促進機構の解明"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:20:08.790767+00:00"}