{"created":"2023-07-27T06:51:58.959197+00:00","id":45636,"links":{},"metadata":{"_buckets":{"deposit":"6dcaa228-c215-40db-8038-161b95c3295d"},"_deposit":{"created_by":18,"id":"45636","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"45636"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00045636","sets":["2812:2813:2820"]},"author_link":["16172","2548"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-06-02","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2012-04-01 - 2014-03-31","bibliographic_titles":[{"bibliographic_title":"平成25(2013)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2013 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では、種々の液相合成法を利用してカーボンドットの合成を行い、ラマン顕微鏡による粒子の観察を行った。その結果、生成粒子は不均一であり、発光しない部分では、炭素材料に特有のDバンドおよびGバンドが観察された。しかしながら、励起光による試料へのダメージが大きく、詳細な検討は困難であった。\n制御性に劣る従来法の欠点を補う新しい合成法として、本研究ではエレクトロスプレーを用いて原料溶液をマイクロ液滴化し、液滴内部で反応を行う新しい手法を新たに開発した。本手法では、エレクトロスプレーの噴霧条件を制御することで、収率の向上および発光特性の制御を実現した。","subitem_description_type":"Abstract"},{"subitem_description":"Carbon dots were synthesized with various methods, and observed with a Raman microscope. It was found that the crude products were inhomogeneous, and the D-band and the G-band were observed in the non-luminescent portion. The sample damage due to the irradiation of the excitation laser was fatal for detailed observation.\nWe have developed a new method of synthesis, where the pyrolysis was conducted in the droplets generated by a pair of electrosprays. The new method enable us to control the reaction more effectively than the conventional method of pyrolysis. We have found that various parameters to control the droplet size were useful to improve the yields and to control the optical properties of the products.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:24760630, 研究期間(年度):2012-04-01 - 2014-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「顕微分光法によるカーボン量子ドットの評価法の開発と環境低負荷溶媒を利用した合成」課題番号24760630\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24760630/24760630seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00051973","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学理工研究域フロンティア工学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=10415789"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=10415789","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24760630/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24760630/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24760630/24760630seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24760630/24760630seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-23"}],"displaytype":"detail","filename":"SC-PR-HIEJIMA-Y-kaken 2014-5p.pdf","filesize":[{"value":"847.1 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-HIEJIMA-Y-kaken 2014-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/45636/files/SC-PR-HIEJIMA-Y-kaken 2014-5p.pdf"},"version_id":"6533ccd9-9b28-4634-b2f1-df2cf6c4ae03"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"顕微分光法によるカーボン量子ドットの評価法の開発と環境低負荷溶媒を利用した合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"顕微分光法によるカーボン量子ドットの評価法の開発と環境低負荷溶媒を利用した合成"},{"subitem_title":"Synthesis of carbon quantum dots in green solvents and evaluation of optical properties by means of spectromicroscopy","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2820"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-08-23"},"publish_date":"2018-08-23","publish_status":"0","recid":"45636","relation_version_is_last":true,"title":["顕微分光法によるカーボン量子ドットの評価法の開発と環境低負荷溶媒を利用した合成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T09:17:54.322960+00:00"}