@article{oai:kanazawa-u.repo.nii.ac.jp:00045839, author = {菅, 拓也 and 宇梶, 裕 and Suga, Takuya and Shimizu, Shoma and Ukaji, Yutaka}, issue = {17}, journal = {Organic Letters}, month = {Aug}, note = {A concise method to directly generate benzyl radicals from benzyl alcohol derivatives has been developed. The simple and inexpensive combination of TiCl4(collidine) (collidine = 2,4,6-collidine) and manganese powder afforded a low-valent titanium reagent, which facilitated homolytic cleavage of benzylic C–OH bonds. The application to radical conjugate addition reactions demonstrated the broad scope of this method. The reaction of various benzyl alcohol derivatives with electron-deficient alkenes furnished the corresponding radical adducts., Embargo Period 12 months, 金沢大学理工研究域物質化学系}, pages = {5389--5392}, title = {Low-Valent Titanium-Mediated Radical Conjugate Addition Using Benzyl Alcohols as Benzyl Radical Sources}, volume = {20}, year = {2018} }