{"created":"2023-07-27T06:52:10.440185+00:00","id":45936,"links":{},"metadata":{"_buckets":{"deposit":"62cf6288-2d96-40dc-9af7-de42ddcc69b5"},"_deposit":{"created_by":18,"id":"45936","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"45936"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00045936","sets":["2812:2813:2815"]},"author_link":["79770","79771"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-09-02","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2016-2018","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 国際共同研究加速基金(国際共同研究強化) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では、スレッディング法による[2]ロタキサンの合成を行った。その結果、ピラー[n]アレーンのバルク液体中に嵩高い末端を有する軸分子を混合し、加熱を行うのみで[2]ロタキサンを形成できることを見出した。輪成分であるピラー[5]アレーンと軸分子との効率的なロタキサン形成に基づき、2つのステーションを異なる長さ・種類のリンカーで連結した[2]ロタキサンを合成した（図4）。得られた[2]ロタキサンについて、鎖長・種類の違いに基づく輪成分のステーション間を移動する速度について検討したところ、シャトリング速度はスペンサーの長さに依存しないことが分かった。","subitem_description_type":"Abstract"},{"subitem_description":"A pillar[5]arene-based pseudo[2]rotaxane was synthesized using a slippage method by only heating an axle with bulky valine derivative ends in a cyclic host liquid, which is liquid at room temperature. The pseudo[2]rotaxane synthesized in a CHL can be converted back to the starting components, i.e., the pillar[5]arene wheel and the axle, by heating in a solvent.\nFor a series of neutral [2]rotaxanes consisting of a pillar[5]arene ring and axles possessing two stations separated by flexible spacers of different lengths, the free energies of activation for the ring shuttling between the stations were found to be independent of the spacer length.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:15KK0185, 研究期間(年度):2016-2018","subitem_description_type":"Other"},{"subitem_description":"出典：「バルク系ホスト－ゲスト化学が拓く次世代超分子マテリアルの創成(国際共同研究強化)」研究成果報告書　課題番号15KK0185\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15KK0185/15KK0185seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052270","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学新学術創成研究機構ナノ生命科学研究所"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=00447682"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=00447682","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15KK0185/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15KK0185/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15KK0185/15KK0185seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15KK0185/15KK0185seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-04-10"}],"displaytype":"detail","filename":"FR-PR-OGOSHI-T-kaken 2019-6p.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"FR-PR-OGOSHI-T-kaken 2019-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/45936/files/FR-PR-OGOSHI-T-kaken 2019-6p.pdf"},"version_id":"43c27afe-33d5-4eca-94e4-f5314e0c5c4e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"バルク系ホスト－ゲスト化学が拓く次世代超分子マテリアルの創成(国際共同研究強化)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"バルク系ホスト－ゲスト化学が拓く次世代超分子マテリアルの創成(国際共同研究強化)"},{"subitem_title":"Construction of new supramolecular assemblies based on host-guest chemistry in bulk state (Fostering Joint International Research)","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-04-10"},"publish_date":"2020-04-10","publish_status":"0","recid":"45936","relation_version_is_last":true,"title":["バルク系ホスト－ゲスト化学が拓く次世代超分子マテリアルの創成(国際共同研究強化)"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:40:55.934502+00:00"}