{"created":"2023-07-27T06:52:10.572309+00:00","id":45940,"links":{},"metadata":{"_buckets":{"deposit":"412ec2e6-d430-4280-a64e-f7e2f916a222"},"_deposit":{"created_by":18,"id":"45940","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"45940"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00045940","sets":["2812:2813:2821"]},"author_link":["79770","79771"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-05-02","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2011-2012","bibliographic_titles":[{"bibliographic_title":"平成24(2012)年度 科学研究費補助金 挑戦的萌芽研究 研究成果報告書"},{"bibliographic_title":"2012 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"軸分子となるビオロゲンポリマーの高分子量化を試みた。しかし、カチオン反応の反応性が低いためか、得られたポリマーは繰り返しユニットが8-10程度のオリゴマーしか得ることができなかった。そこで、主鎖をポリTHFへと変更し、ポリロタキサンの合成を試みた。その結果、液体であるトリエチレンオキシド鎖導入Pillar[5]areneに軸分子を混合し、キャッピング反応を行うことで、ポリロタキサンを得ることに成功した。イオン性基を含有していないPillar[5]areneからなるポリロタキサンの初めての合成例である。","subitem_description_type":"Abstract"},{"subitem_description":"We firstly tried to synthesize viologen polymers with high molecular weights. However, due to the low reactivity of the cationic reaction, the degree of polymerization (DP) was found to be 8-10. Thus, we synthesized the other pillar[5]arene-based polyrotaxanes containing polyTHF. By capping polyTHF end groups with bulky stoppers in liquid pillar[5]arene carrying 10 triethylene oxide chains, new nonionic polyrotaxanes consisting of polyTHF and pillar[5]arene wheels carrying 10 triethylene oxide chains could be synthesized.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:23655210, 研究期間(年度):2011-2012","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「ロタキサン型フェノール樹脂を基にした環動部位を有する熱硬化性樹脂の創成」課題番号23655210\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23655210/23655210seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052274","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学新学術創成研究機構ナノ生命科学研究所"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=00447682"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=00447682","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23655210/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23655210/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23655210/23655210seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23655210/23655210seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-09-28"}],"displaytype":"detail","filename":"SC-PR-OGOSHI-T-kaken 2013-4p.pdf","filesize":[{"value":"378.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-OGOSHI-T-kaken 2013-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/45940/files/SC-PR-OGOSHI-T-kaken 2013-4p.pdf"},"version_id":"a37cc48a-8e8f-46f2-949f-cafb9cfce32d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"ロタキサン型フェノール樹脂を基にした環動部位を有する熱硬化性樹脂の創成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ロタキサン型フェノール樹脂を基にした環動部位を有する熱硬化性樹脂の創成"},{"subitem_title":"Construction of Thermo-setting Phenolic Resin Containing Sliding Unit Segments","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2821"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-01"},"publish_date":"2018-10-01","publish_status":"0","recid":"45940","relation_version_is_last":true,"title":["ロタキサン型フェノール樹脂を基にした環動部位を有する熱硬化性樹脂の創成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:31:58.971341+00:00"}