{"created":"2023-07-27T06:52:18.182540+00:00","id":46132,"links":{},"metadata":{"_buckets":{"deposit":"b3b8b4de-4e4d-4e24-b9e0-dbbcbe51658f"},"_deposit":{"created_by":18,"id":"46132","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46132"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046132","sets":["2812:2813:2817"]},"author_link":["80000","2561"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-06-02","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2014-04-01 - 2017-03-31","bibliographic_titles":[{"bibliographic_title":"平成28(2016)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2016 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"生体系では，メタンモノオキシゲナーゼ（MMO） や トルエンモノオキシゲナーゼ（TMO）が二核鉄中心により酸素分子を活性化して，アルカンやアレーン類の水酸化をいとも簡単に行っている．本研究では，MMOやTMOのペルオキソ中間体の機能モデルとなる二核鉄(III)ペルオキソ錯体を創製し，コア構造によるペルオキソ錯体の反応性の制御を目指して，外部基質との酸化反応性の検討を行った．","subitem_description_type":"Abstract"},{"subitem_description":"The Fe2/O2-mediated oxidation reactions such as arene hydroxylation and C-H bond oxidation of alkanes are of current interest for understanding the reaction mechanism of dioxygen activating non-heme diiron enzymes such as soluble methane monooxygenase (sMMO) and toluene monooxygenase (TMO) and utilizing metal complexes as oxidation catalysis. Various synthetic (peroxo)diiron(III) model complexes have been developed, however, there are few functional models that exhibit oxidation reactivity and O-O bond cleavage similar to those of (peroxo)diiron(III) species in non-heme diiron enzymes. In this study, (peroxo)diiron(III) complexes having a bridging ligand (oxo or carboxylate) were prepared and their oxidation reacvtivities towards external substrates were studied. We found a mechanistic evidence that a diiron(IV)-oxo species derived from the O-O bond cleavage of (peroxo)diiron(III) species is involved in the oxidation reaction as an active oxidant.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:26410067, 研究期間(年度):2014-04-01 - 2017-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「二核鉄ペルオキソ錯体のコア構造による反応性の制御」研究成果報告書　課題番号26410067\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26410067/26410067seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052466","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40332663"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40332663","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26410067/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26410067/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26410067/26410067seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26410067/26410067seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-10-15"}],"displaytype":"detail","filename":"SC-PR-FURUTACHI-H-kaken 2017-5p.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-FURUTACHI-H-kaken 2017-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46132/files/SC-PR-FURUTACHI-H-kaken 2017-5p.pdf"},"version_id":"bf541c68-ba50-4aa0-a7be-2fce4bee25a2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"二核鉄ペルオキソ錯体のコア構造による反応性の制御","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"二核鉄ペルオキソ錯体のコア構造による反応性の制御"},{"subitem_title":"Control of oxidation reactivity of (peroxo)diiron complexes","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2817"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-15"},"publish_date":"2018-10-15","publish_status":"0","recid":"46132","relation_version_is_last":true,"title":["二核鉄ペルオキソ錯体のコア構造による反応性の制御"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T11:09:28.499367+00:00"}