{"created":"2023-07-27T06:52:18.227724+00:00","id":46133,"links":{},"metadata":{"_buckets":{"deposit":"6774d21c-d7bf-416d-9aab-fd1905b1e797"},"_deposit":{"created_by":18,"id":"46133","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46133"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046133","sets":["2812:2813:2820"]},"author_link":["80000","2561"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-06-02","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2011-2013","bibliographic_titles":[{"bibliographic_title":"平成25(2013)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2013 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では，様々なコア構造を有する二核鉄(III)ペルオキソ錯体の合成に成功とそれらの様々な外部基質に対する酸化反応性を調べた．その結果，カルボン酸イオンを含む二核鉄(III)ペルオキソ錯体は，様々なC-H結合解離エネルギー (BDE) を持つ脂肪族化合物に対して酸化能を持つことが明らかとなった．さらに単核鉄(III)過酢酸錯体の合成と結晶構造解析に成功し，この種の酸化反応性は高くないが，オレフィン類のエポキシ化に加えて，アダマンタンの３級C-H結合を酸化することが明らかとなった．","subitem_description_type":"Abstract"},{"subitem_description":"(peroxo)Fe(III)2 complexes having various core structures were prepared and their oxidation reactivity towards external substrates were investigated. (peroxo)Fe(III)2 complex with a triphenylacetate bridge is capable of the oxidation of aliphatic C-H bonds having BDEs from 74-92 kcal/mol. A mononuclear peracetatoiron(III) complex with a tripodal ligand was also prepared. This comples is the first example of a structurally and spectroscopically well-defined non-heme type peracetatoiron(III) complex and has modest oxidation ability toward triphenyl phosphine, some olefins, and the tertiary C-H bond of adamantane.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:23550071, 研究期間(年度):2011-2013","subitem_description_type":"Other"},{"subitem_description":"出典：「様々なコア構造を持つ二核鉄ペルオキソ錯体の創製および酸化特異性の解明」研究成果報告書　課題番号23550071\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23550071/23550071seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052467","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学理工研究域物質化学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40332663"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40332663","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23550071/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23550071/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23550071/23550071seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23550071/23550071seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-10-15"}],"displaytype":"detail","filename":"SC-PR-FURUTACHI-H-kaken 2014-4p.pdf","filesize":[{"value":"959.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-FURUTACHI-H-kaken 2014-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46133/files/SC-PR-FURUTACHI-H-kaken 2014-4p.pdf"},"version_id":"0020a907-bccb-40ad-935f-d8059cbc6517"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"様々なコア構造を持つ二核鉄ペルオキソ錯体の創製および酸化特異性の解明","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"様々なコア構造を持つ二核鉄ペルオキソ錯体の創製および酸化特異性の解明"},{"subitem_title":"Synthesis of (peroxo)diiron(III) complexes having various core structures","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2820"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-15"},"publish_date":"2018-10-15","publish_status":"0","recid":"46133","relation_version_is_last":true,"title":["様々なコア構造を持つ二核鉄ペルオキソ錯体の創製および酸化特異性の解明"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T09:12:20.182205+00:00"}