{"created":"2023-07-27T06:52:25.323607+00:00","id":46323,"links":{},"metadata":{"_buckets":{"deposit":"ee2da5f2-02a7-449c-a78d-2bf81577de39"},"_deposit":{"created_by":18,"id":"46323","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46323"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046323","sets":["2812:2813:2816"]},"author_link":["3005","16527"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05-23","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2015-04-01 - 2018-03-31","bibliographic_titles":[{"bibliographic_title":"平成29(2017)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2017 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Furuyama, Taniyuki"}],"nameIdentifiers":[{"nameIdentifier":"16527","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30584528","nameIdentifierScheme":"金沢大学研究者情報","nameIdentifierURI":"http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=30584528"},{"nameIdentifier":"30584528","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000030584528"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"アザポルフィリンの合成・機能開発における典型元素の可能性について、多角的な視点から検討を行った。中心に五価リンを導入したある種の錯体は容易に一電子還元を受け、空気中安定なラジカルを得ることができた。続いて、硫黄を用いた新規反応を開発し、1. 20π反芳香族性を持つ拡張フタロシアニン、および2. 近赤外光を強く吸収できるフタロシアニンへの機能性部位の導入、に成功した。また、元素特性に立脚した新規フタロシアニン合成法を適用し、電子受容性フタロシアニンの合成に始めて成功した。一部の化合物は近赤外光による高い酸素増感能を示した。","subitem_description_type":"Abstract"},{"subitem_description":"The effects of main-group elements in the synthesis and properties of azaporphyrins have been investigated. The tetraazaporphyrin phosphorus(V) complex was reduced by addition of base, and extremely air-stable neutral radical (formally 19π electrons) could be isolated. Two novel synthetic reactions mediated sulfur have been developed. 1. A diamino-beta-isoindigo skeleton was obtained directly from phthalonitriles, and a new antiaromatic expanded phthalocyanine skeleton (pentabenzotriazasmaragdyrin, PBTAS) was obtained by the condensation with such isoindigo and other phthalonitrile. 2. Three-component coupling reaction of element sulfur, organometallic reagents, and phthalonitrile was developed, and functionalized phthalocyanines that have an intense absorption band in the near-IR region have been synthesized. Electron-withdrawing phthalocyanines were synthesized by lead-mediated reactions. Some metal complexes have high efficiency of singlet oxygen generation.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:15K05409, 研究期間(年度):2015-04-01 - 2018-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「典型元素アザポルフィリノイドの合成および機能開発」課題番号15K05409\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K05409/15K05409seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052656","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=30584528"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=30584528","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K05409/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K05409/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K05409/15K05409seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K05409/15K05409seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"古山, 渓行"}],"nameIdentifiers":[{"nameIdentifier":"3005","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30584528","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=30584528"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-26"}],"displaytype":"detail","filename":"SC-PR-FURUYAMA-T-kaken 2018-5p.pdf","filesize":[{"value":"493.3 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-FURUYAMA-T-kaken 2018-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46323/files/SC-PR-FURUYAMA-T-kaken 2018-5p.pdf"},"version_id":"15946d85-8bf8-43d5-a299-77714f7088df"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"典型元素アザポルフィリノイドの合成および機能開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"典型元素アザポルフィリノイドの合成および機能開発"},{"subitem_title":"Development of Azaporphyrin Main-Group Element complexes","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2816"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-04-26"},"publish_date":"2019-04-26","publish_status":"0","recid":"46323","relation_version_is_last":true,"title":["典型元素アザポルフィリノイドの合成および機能開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:32:33.764508+00:00"}