{"created":"2023-07-27T06:52:25.367362+00:00","id":46324,"links":{},"metadata":{"_buckets":{"deposit":"c9e02c9e-a620-4ec8-bfc7-755c13d69243"},"_deposit":{"created_by":18,"id":"46324","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46324"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046324","sets":["2812:2813:2819"]},"author_link":["3005","16527"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-06-10","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2012-04-01 - 2015-03-31","bibliographic_titles":[{"bibliographic_title":"平成26(2014)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2014 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Furuyama, Taniyuki"}],"nameIdentifiers":[{"nameIdentifier":"16527","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30584528","nameIdentifierScheme":"金沢大学研究者情報","nameIdentifierURI":"http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=30584528"},{"nameIdentifier":"30584528","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000030584528"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"フタロシアニン等のピロール、インドールがオリゴマー化した化合物は顕著な光特性を持つことが知られている。本研究では可視・近赤外光の制御を目指し、主に15, 16族典型元素を用いた新規化合物の合成と機能評価を行った。16族元素についてはチオフェン-ピロール型オリゴマーの合成に成功し、高い蛍光量子収率を持つことや、更なるオリゴマー化により可視域の広い範囲の光を強く吸収できることを示した。また15族元素についてはある種のフタロシアニンリン錯体において、吸収極大が1000 nmを超える領域に現れることを見いだし、新規近赤外色素の指針を得ることができた。","subitem_description_type":"Abstract"},{"subitem_description":"Oligoheterole derivatives, such as phthalocyanines (Pc) and aza-dipyrromethenes show unique optical properties. In this research, novel oligoheteroles with main-group elements have been synthesized to tune optical properties in the visible to near-IR region. At first, the synthesis of aza-bridged thiophene-pyrrole dyads (so-called core-modified aza-dipyrromethene) has been succeeded from a stable diaminothiophene. The dyads showed intense fluorescence and a triad, which could absorb over a wide range of the visible to near-IR region, was also synthesized. Secondly, phosphorus(V) complexes of group 16 alpha-substituted Pcs showed a single intense band peak beyond 1000 nm. The Pcs are easy to synthesize, robust, free-from transition metals, and have predictable properties. The novel strategy could be broadly useful in the design of near-IR dyes and pigments.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:24750031, 研究期間(年度):2012-04-01 - 2015-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「典型元素の性質を利用した機能性オリゴへテロールの開発」研究成果報告書　課題番号24750031\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24750031/24750031seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052657","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=30584528"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=30584528","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24750031/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24750031/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24750031/24750031seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24750031/24750031seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"古山, 渓行"}],"nameIdentifiers":[{"nameIdentifier":"3005","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30584528","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=30584528"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-05"}],"displaytype":"detail","filename":"SC-PR-FURUYAMA-T-kaken 2015-5p.pdf","filesize":[{"value":"176.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-FURUYAMA-T-kaken 2015-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46324/files/SC-PR-FURUYAMA-T-kaken 2015-5p.pdf"},"version_id":"bdb13093-9482-4e44-be3c-0128260c187c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"典型元素の性質を利用した機能性オリゴへテロールの開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"典型元素の性質を利用した機能性オリゴへテロールの開発"},{"subitem_title":"Development of Functional Oligoheteroles with Main-Group Elements","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2819"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-11-05"},"publish_date":"2018-11-05","publish_status":"0","recid":"46324","relation_version_is_last":true,"title":["典型元素の性質を利用した機能性オリゴへテロールの開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:46:02.216784+00:00"}