{"created":"2023-07-27T06:52:30.557575+00:00","id":46475,"links":{},"metadata":{"_buckets":{"deposit":"702660de-0f9f-4cf8-b907-2cbd8b8af4ce"},"_deposit":{"created_by":18,"id":"46475","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46475"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046475","sets":["2812:2813:2816"]},"author_link":["80501","80500"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-04-16","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2015-04-01 - 2018-03-31","bibliographic_titles":[{"bibliographic_title":"平成29(2017)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2017 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"グリーンケミストリーを指向した反応プロセスの構築において、フルオラス溶媒やイオン液体を利用する手法が期待されている。本研究ではこれら二つの特性を兼ね備えたフルオラスなイオン液体の創製を検討した。ピロリジンまたはピペリジンの窒素原子上、およびピリジン環の炭素上にトリデカフルオロオクチル基を２つ導入して合成した塩類は、高いフルオラス性をもったイオン液体として利用できること明らかにした。また、ケイ素原子上にパーフルオロアルキル基を３つ有するシリル基を導入するといずれも高いフルオラス性を示した。","subitem_description_type":"Abstract"},{"subitem_description":"Fluorous chemistry has been expected as one of the promising fields of green chemistry. In particular the synthesis of fluorous ionic liquids possessing perfluoroalkyl groups has received growing attention. Here, the synthesis of a novel class of fluorous ionic liquids was investigated. The reaction of pyrrolidine or piperidine with an excess amount of perfluoroalkyl iodide proceeded to give the corresponding iodide salts possessing two perfluoroalkyl groups on nitrogen atom in good yields. On the other hand, the reaction of dibromopyridine with perfluoroalkyl iodide and the following treatment with alkyl iodide gave the corresponding pyridinium salts having two perfluoroalkyl groups on pyridine ring. The anion exchange of the resulting iodides gave the ionic liquids with high fluorophilicity. The pyrrolidinium, piperidinium, and pyridinium ionic liquids possessing tri(perfluoroalkyl)silyl group also have a high fluorophilicity regardless of their structures.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:15K05585, 研究期間(年度):2015-04-01 - 2018-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「フルオラスケミストリーを指向した新規イオン液体の創製」課題番号15K05585\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K05585/15K05585seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00052807","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=60242533"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=60242533","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K05585/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K05585/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K05585/15K05585seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-15K05585/15K05585seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-26"}],"displaytype":"detail","filename":"SC-PR-HONDA-M-kaken 2018-5p.pdf","filesize":[{"value":"231.7 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-HONDA-M-kaken 2018-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46475/files/SC-PR-HONDA-M-kaken 2018-5p.pdf"},"version_id":"922bbd51-caf5-4383-b998-50a64619f63e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"フルオラスケミストリーを指向した新規イオン液体の創製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フルオラスケミストリーを指向した新規イオン液体の創製"},{"subitem_title":"Developments of New Ionic Liquids Directed towards Fluorous Chemistry","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2816"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-04-26"},"publish_date":"2019-04-26","publish_status":"0","recid":"46475","relation_version_is_last":true,"title":["フルオラスケミストリーを指向した新規イオン液体の創製"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:47:18.705618+00:00"}