{"created":"2023-07-27T06:52:39.593300+00:00","id":46725,"links":{},"metadata":{"_buckets":{"deposit":"7869f788-5d0d-4dd7-a03e-0ce36c06b2c0"},"_deposit":{"created_by":18,"id":"46725","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46725"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046725","sets":["2812:2813:2819"]},"author_link":["78869","78868"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-06-11","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2013-04-01 - 2015-03-31","bibliographic_titles":[{"bibliographic_title":"平成26(2014)年度 科学研究費補助金 挑戦的萌芽研究 研究成果報告書"},{"bibliographic_title":"2014 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohmiya, Hirohisa"}],"nameIdentifiers":[{"nameIdentifier":"78869","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40508876","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40508876"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究者は、不飽和化合物であるアルキン誘導体を出発原料とした銅(I)触媒反応の開発を検討した。その結果、9-BBN型アルキルボラン/アルキノエート/スズアルコキシドの銅(I)触媒高選択的三成分カップリング反応を用いたアルケニルスズ化合物の合成法を開発した。さらに、分子状水素を用いた内部アルキンの銅/N-ヘテロ環カルベン錯体触媒シン選択的水素化反応を見出した。","subitem_description_type":"Abstract"},{"subitem_description":"The researcher examined copper(I)-catalyzed reactions using alkyne substrates. As a result, a copper-catalyzed three-component coupling with alkylboranes, alkynoates, and tributyltin methoxide was developed as a versatile route to trisubstituted alkenylstannanes. Additionally, syn-selective hydrogenation of internal alkynes with molecular hydrogen under the influence of a catalytic amount of copper complexes was achieved.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:25620072, 研究期間(年度):2013-04-01 - 2015-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「不飽和炭化水素類の環境調和型分子変換反応の開発」課題番号25620072\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620072/25620072seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00053057","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40508876"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40508876","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620072/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620072/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620072/25620072seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620072/25620072seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"大宮, 寛久"}],"nameIdentifiers":[{"nameIdentifier":"78868","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40508876","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40508876"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-01-10"}],"displaytype":"detail","filename":"ME-PR-OHMIYA-H-kaken 2015-4p.pdf","filesize":[{"value":"307.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"ME-PR-OHMIYA-H-kaken 2015-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46725/files/ME-PR-OHMIYA-H-kaken 2015-4p.pdf"},"version_id":"731d3475-2f66-4e3e-add1-8b0878b9798e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"不飽和炭化水素類の環境調和型分子変換反応の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"不飽和炭化水素類の環境調和型分子変換反応の開発"},{"subitem_title":"Development of Environmentally-friendly Molecular Transformations of Unsaturated Compounds","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2819"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-01-10"},"publish_date":"2019-01-10","publish_status":"0","recid":"46725","relation_version_is_last":true,"title":["不飽和炭化水素類の環境調和型分子変換反応の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:45:51.831088+00:00"}