{"created":"2023-07-27T06:52:39.638037+00:00","id":46726,"links":{},"metadata":{"_buckets":{"deposit":"192ea998-ca9f-453b-8442-8461c6078291"},"_deposit":{"created_by":18,"id":"46726","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46726"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046726","sets":["2812:2813:2819"]},"author_link":["78869","78868"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-06-11","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2012-04-01 - 2015-03-31","bibliographic_titles":[{"bibliographic_title":"平成26(2014)年度 科学研究費補助金 若手研究(A) 研究成果報告書"},{"bibliographic_title":"2014 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohmiya, Hirohisa"}],"nameIdentifiers":[{"nameIdentifier":"78869","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40508876","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40508876"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究者は、金属の酸化数が変化しにくいという銅元素の化学反応における特徴を活かした合理的触媒設計により、汎用性の高い有機ホウ素化合物を用いた高選択的合成反応を開発した。そしてこれらを不斉炭素－炭素結合形成反応に展開した。たとえば、世界初であるアルキルホウ素化合物の不斉アリル化や不斉共役付加を見出した。近年では、有機化合物に最も豊富に存在する炭素－水素結合の利用に着目し、これらの立体選択的変換反応を開発した。本研究は、銅触媒の化学の可能性を開拓した先駆的なものであり、銅触媒反応の新たな設計指針を打ち立てることで当該分野の拡大発展に大きく貢献した。","subitem_description_type":"Abstract"},{"subitem_description":"The researcher developed unprecedented synthetic reactions based on the catalyst design focusing on a characteristic feature of copper that is relatively resistant to oxidation state change. Specifically, he developed new types of highly selective carbon-carbon bond formation reactions of organoboron compounds with copper catalyst systems. This research has been expanded to catalytic enantioselective carbon-carbon bond formation reactions. The focus of the research has shifted to catalytic C-H functionalization for stereoselective carbon-carbon bond formation reactions. The achievement has pioneered the potential of copper chemistry, and established new designing concepts of copper catalysis.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:24685015, 研究期間(年度):2012-04-01 - 2015-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「機能分子合成を指向した化学選択的炭素－炭素結合形成反応の開発」課題番号24685015\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24685015/24685015seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00053058","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40508876"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40508876","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24685015/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24685015/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24685015/24685015seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-24685015/24685015seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"大宮, 寛久"}],"nameIdentifiers":[{"nameIdentifier":"78868","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40508876","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40508876"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-01-10"}],"displaytype":"detail","filename":"ME-PR-OHMIYA-H-kaken 2015A-4p.pdf","filesize":[{"value":"398.9 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"ME-PR-OHMIYA-H-kaken 2015A-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46726/files/ME-PR-OHMIYA-H-kaken 2015A-4p.pdf"},"version_id":"2b2a1796-ab69-436e-835e-0253df892650"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"機能分子合成を指向した化学選択的炭素－炭素結合形成反応の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"機能分子合成を指向した化学選択的炭素－炭素結合形成反応の開発"},{"subitem_title":"Development of Chemoselective Carbon-Carbon Bond Formation Reactions Directed toward Synthesis of Functional Molecules","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2819"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-01-10"},"publish_date":"2019-01-10","publish_status":"0","recid":"46726","relation_version_is_last":true,"title":["機能分子合成を指向した化学選択的炭素－炭素結合形成反応の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:45:52.069760+00:00"}