{"created":"2023-07-27T06:52:46.449192+00:00","id":46886,"links":{},"metadata":{"_buckets":{"deposit":"c314dc7a-a728-4ea6-9976-beb96d5a2f35"},"_deposit":{"created_by":18,"id":"46886","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"46886"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00046886","sets":["2812:2813:2820"]},"author_link":["277","81690"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-06-04","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2011-04-01 - 2014-03-31","bibliographic_titles":[{"bibliographic_title":"平成25(2013)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2013 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"両親媒性環状化合物を合成し、凝集状態に及ぼす分子構造の影響と環状化合物を用いた分子カプセルの形成および分子カプセルの３次元配列制御について検討した。両親媒性カリックスアレーンの場合、アルキル鎖長によって凝集状態が変化することおよび分子カプセルの形成には最適のアルキル鎖長があることを解明した。さらに、液晶性シクロデキストリン (LCCD)を合成し、液晶性を利用して分子カプセルを規則的に配列させる方法を検討した。βLCCDがスメクチック液晶構造をとり、環状骨格を層状に規則的に配列させることが可能となった。これは、分子カプセルの規則的な３次元配列を可能とする分子集積技術へと応用される。","subitem_description_type":"Abstract"},{"subitem_description":"Amphiphilic calix[4]resorcinarenes (ampCR) were prepared from resorcinol and aldehydes with alkyl chain under acidic conditions. AmpCR will be a desirable building block of molecular capsules. The ampCR with decyl side chains showed sol-gel transition in diethylene glycol (DEG) by heating and/or cooling solution. The aggregation behavior of ampCR depended on the length of side chain. It was found that the effective encapsulation of ampCR needed a suitable length of alkyl chains. Liquid crystalline cyclodextrins (LCCDs) were prepared by introducing mesogen groups to CDs. LCCD formed a smectic type of thermotropic mesophses with layered regular assembly and orientation. The self-assembly of capsules obtained from LCCDs will be controlled by liquid crystalline structure, depending on the size of CD. The liquid crystalline capsules will achieve regular orientation of molecule involved in the capsule and develop new functional properties such as a quantum effect.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:23350051, 研究期間(年度):2011-04-01 - 2014-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「分子カプセルを利用した３次元規則性超分子構造体の作成と機能開発」研究成果報告書　課題番号23350051\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23350051/23350051seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00053213","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学理工研究域物質化学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=90220251"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=90220251","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23350051/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23350051/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23350051/23350051seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-23350051/23350051seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-22"}],"displaytype":"detail","filename":"SC-PR-YAMADA-T-kaken 2014-5p.pdf","filesize":[{"value":"707.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-YAMADA-T-kaken 2014-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/46886/files/SC-PR-YAMADA-T-kaken 2014-5p.pdf"},"version_id":"fa258762-2750-4431-b111-60ac0961fe01"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"分子カプセルを利用した３次元規則性超分子構造体の作成と機能開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"分子カプセルを利用した３次元規則性超分子構造体の作成と機能開発"},{"subitem_title":"Preparation of supramolecular assembly with regular structure obtained by encapsulation of cyclic molecules and development of its functionality","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2820"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-02-22"},"publish_date":"2019-02-22","publish_status":"0","recid":"46886","relation_version_is_last":true,"title":["分子カプセルを利用した３次元規則性超分子構造体の作成と機能開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T09:10:49.284187+00:00"}