{"created":"2023-07-27T06:53:21.299188+00:00","id":47901,"links":{},"metadata":{"_buckets":{"deposit":"440a86a9-6b7b-46c0-9757-0be7cd2e72de"},"_deposit":{"created_by":18,"id":"47901","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"47901"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00047901","sets":["2812:2813:2815"]},"author_link":["78864","2945"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-06-04","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2017-04-01 - 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2008)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yasuda, Shigeo"}],"nameIdentifiers":[{"nameIdentifier":"78864","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40647038","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40647038"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"初期計画に沿って、(1) アレン-アルキン-アルキンを用いる環構築反応の天然物合成への応用、及び (2) アレン-アルケンの分子内環化反応の分子間反応への拡張を試みた。\n(1) の研究では天然物合成を達成することはできなかったものの、標的天然物の主骨格となる5/5/5員環骨格を低収率ながら合成することができた。(2) の研究では目的の分子間[2+2+2]環化付加反応の開発に成功した。さらに不斉触媒を利用することにより、不斉環化反応への拡張にも成功した。","subitem_description_type":"Abstract"},{"subitem_description":"In line with the initial plan, (1) application of ring-closing reaction to natural product synthesis using allene-alkyne-alkyne, and (2) extension of intramolecular cyclization of allene-alkene to intermolecular reaction were attempted.\nAlthough the natural product synthesis could not be achieved in the study of (1), it was possible to synthesize a 5/5/5-membered ring skeleton as a main skeleton of the target natural product. In the study of (2), we succeeded in developing the target intermolecular [2 + 2 + 2] cycloaddition reaction. Furthermore, we have succeeded in extending to asymmetric cyclization reaction by using an asymmetric catalyst.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:17K15422, 研究期間(年度):2017-04-01 - 2019-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「アレンを基軸とする新規環構築法の開発」課題番号17K15422\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K15422/17K15422seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00054224","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40647038"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40647038","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K15422/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K15422/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K15422/17K15422seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K15422/17K15422seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安田, 茂雄"}],"nameIdentifiers":[{"nameIdentifier":"2945","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40647038","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40647038"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-04-17"}],"displaytype":"detail","filename":"PH-PR-YASUDA-S-kaken 2019-4p.pdf","filesize":[{"value":"106.5 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-YASUDA-S-kaken 2019-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/47901/files/PH-PR-YASUDA-S-kaken 2019-4p.pdf"},"version_id":"773876aa-6d9e-45aa-9112-1fdf02f0cfd7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"アレンを基軸とする新規環構築法の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アレンを基軸とする新規環構築法の開発"},{"subitem_title":"New Entries to Ring Construction Based on Allene Chemistry","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-04-17"},"publish_date":"2020-04-17","publish_status":"0","recid":"47901","relation_version_is_last":true,"title":["アレンを基軸とする新規環構築法の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:30:18.643178+00:00"}