{"created":"2023-07-27T06:53:28.867703+00:00","id":48198,"links":{},"metadata":{"_buckets":{"deposit":"ff3fc8cc-ec0c-4800-b37f-78dcf2fa7e5f"},"_deposit":{"created_by":18,"id":"48198","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"48198"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00048198","sets":["2812:2813:2815"]},"author_link":["76425","76426"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-22","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2016-04-01 - 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"トリアジニルアンモニウム塩を基盤とする光励起型アルキルラジカル発生法を開発した。トリアジニルアンモニウム塩に対するUV照射による直接的なラジカル発生は種々検討した結果、困難であることが明らかになった。一方で、ある種の金属光レドックス触媒と還元剤存在下、可視光を照射すると、トリアジニルアンモニウム塩からアルキルラジカルが発生し、共存するマイケルアクセプターと反応し目的の付加体を収率73%で与えることを明らかにした。 ","subitem_description_type":"Abstract"},{"subitem_description":"I have developed a method for photo-induced alkyl radical generation based on triazinylammonium salt. Direct radical generation by UV irradiation to triazinylammonium salt has proved to be difficult. On the other hand, the reaction of triazinylammonium salt in the presence of a metal photoredox catalyst and a reducing agent under visible light irradiation allowed to generate the alkyl radical, which subsequently reacted with the coexisting Michael acceptor to give the desired adduct in a 73% yield.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:16K08160, 研究期間(年度):2016-04-01 - 2019-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「トリアジニルアンモニウム塩を基盤とする光励起ラジカル発生法の開発」課題番号16K08160\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08160/16K08160seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00054520","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=40583232"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40583232","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K08160/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K08160/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08160/16K08160seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08160/16K08160seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-04-23"}],"displaytype":"detail","filename":"PH-PR-YAMADA-K-kaken 2019-5p.pdf","filesize":[{"value":"490.7 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-YAMADA-K-kaken 2019-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/48198/files/PH-PR-YAMADA-K-kaken 2019-5p.pdf"},"version_id":"71e811ca-79cb-4ded-8f9e-01236fe5d085"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"トリアジニルアンモニウム塩を基盤とする光励起ラジカル発生法の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"トリアジニルアンモニウム塩を基盤とする光励起ラジカル発生法の開発"},{"subitem_title":"Development of photo-induced radical generation based on triazinylammonium salt","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-04-23"},"publish_date":"2020-04-23","publish_status":"0","recid":"48198","relation_version_is_last":true,"title":["トリアジニルアンモニウム塩を基盤とする光励起ラジカル発生法の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:36:39.144291+00:00"}