{"created":"2023-07-27T06:53:28.935450+00:00","id":48200,"links":{},"metadata":{"_buckets":{"deposit":"bb22186c-24a3-409b-8545-19558d1073ac"},"_deposit":{"created_by":18,"id":"48200","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"48200"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00048200","sets":["2812:2813:2815"]},"author_link":["26926","1882"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-15","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2016-04-01 - 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究代表者はベンザイン種との安定ボラン錯体との反応を検討し、p-ベンザインの1,4-ヒドロホウ素化反応が進行することを見出した。また、この研究の過程で以下の三つの反応を発見した：（１）ボリルラジカルのアルキンへの付加を伴うラジカル環化反応、（２）アルキンのラジカル的trans-ヒドロホウ素化反応、（３）ボリルラジカルを用いるプロパルギルアセテート誘導体のラクトン化反応。 ","subitem_description_type":"Abstract"},{"subitem_description":"We found 1,4-hydroboration of p-benzyne species with stable borane complexes. In the course of this study, we discovered three new reactions: (1) radical cyclization induced by addition of boryl radicals to alkynes, (2) radical trans-hydroboration of alkynes, (3) lactonization of propargyl acetates using boryl radicals.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:16K08159, 研究期間(年度):2016-04-01 - 2019-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「高反応性活性種の新たな活用法に立脚した化学反応開発」課題番号16K08159\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08159/16K08159seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00054522","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=60444204"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=60444204","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K08159/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K08159/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08159/16K08159seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08159/16K08159seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-04-23"}],"displaytype":"detail","filename":"PH-PR-TANIGUCHI-T-kaken 2019-6p.pdf","filesize":[{"value":"374.6 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-TANIGUCHI-T-kaken 2019-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/48200/files/PH-PR-TANIGUCHI-T-kaken 2019-6p.pdf"},"version_id":"af03aa90-d36f-4d01-bb39-a427eb7f01d3"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"高反応性活性種の新たな活用法に立脚した化学反応開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"高反応性活性種の新たな活用法に立脚した化学反応開発"},{"subitem_title":"Development of Reactions Based on New Utilization of Highly Reactive Species","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-04-23"},"publish_date":"2020-04-23","publish_status":"0","recid":"48200","relation_version_is_last":true,"title":["高反応性活性種の新たな活用法に立脚した化学反応開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:36:37.605903+00:00"}