{"created":"2023-07-27T06:53:34.641911+00:00","id":48351,"links":{},"metadata":{"_buckets":{"deposit":"436d2adc-3240-45e2-a901-20e2069f472d"},"_deposit":{"created_by":18,"id":"48351","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"48351"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00048351","sets":["2812:2813:2815"]},"author_link":["86133","86132"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-30","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2016-04-01 - 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"ピラー[6]アレーン結晶を吸着材として用いると17％イソオクタン蒸気を用いた場合には、＞99％純度にまでイソオクタンの純度を向上させることができた。またピラー[5]アレーンの1ユニットを酸化したピラー[5]アレーン結晶は、1,4-ジエトキシベンゼンとの電荷移動錯体を形成しているために、茶色を呈色していた。そこにアルカン分子蒸気を導入すると、直鎖のアルカン分子蒸気の場合は、茶色から赤色へと色変化を示した。これにより、これまでは色変化で検知が困難であったアルカンを検知することに成功した。ピラー[5]アレーン結晶は、様々な分子量のPEOの中から選択的に高分子量体のみを取り込むことを見出した。 ","subitem_description_type":"Abstract"},{"subitem_description":"The research octane number was dramatically improved from a low research octane number(17%) to a high research octane number (>99%) using the activated crystals of pillar[6]arene. Colored crystals of pillar[5]arene containing one benzoquinone unit were found to exhibit alkane-shape-selective vapochromic behavior. Activated pillar[5]arene crystals, prepared by removing solvated methanol from pillar[5]arene crystals, changed color from dark-brown to light-red after exposure to linear alkane vapors; however, no color changes were observed on exposure to branched or cyclic alkanes. The activated pillar[5]arene crystals are immersed in melted PEO, causing the crystals to selectively take up PEO with high mass fraction. The high mass fractionation is caused by the greater number of attractive CH/π interactions between PEO C-H groups and the π-electron-rich 1D channel of the pillar[5]arene with increasing PEO chain length. ","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:16H04130, 研究期間(年度):2016-04-01 - 2019-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「結晶状態のホスト－ゲスト化学を基盤とした分子の濃縮・分離システムの創製」課題番号16H04130\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16H04130/16H04130seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00054673","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学新学術創成研究機構ナノ生命科学研究所"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=00447682"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=00447682","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16H04130/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16H04130/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16H04130/16H04130seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16H04130/16H04130seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-04-24"}],"displaytype":"detail","filename":"SC-PR-OGOSHI-T-kaken 2019-6p.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-OGOSHI-T-kaken 2019-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/48351/files/SC-PR-OGOSHI-T-kaken 2019-6p.pdf"},"version_id":"0be33b10-afd7-457a-9d3d-4b6bfa1f8a4a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"結晶状態のホスト－ゲスト化学を基盤とした分子の濃縮・分離システムの創製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"結晶状態のホスト－ゲスト化学を基盤とした分子の濃縮・分離システムの創製"},{"subitem_title":"Construction of Molecular Separation and Condensation Systems Based on Host-Guest Chemistry in the Crystalline State","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-04-24"},"publish_date":"2020-04-24","publish_status":"0","recid":"48351","relation_version_is_last":true,"title":["結晶状態のホスト－ゲスト化学を基盤とした分子の濃縮・分離システムの創製"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:35:25.746429+00:00"}