{"created":"2023-07-27T06:53:53.127879+00:00","id":48922,"links":{},"metadata":{"_buckets":{"deposit":"1e67ad1a-ac95-45d5-bbb3-d03e4603bcc0"},"_deposit":{"created_by":18,"id":"48922","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"48922"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00048922","sets":["934:935:936"]},"author_link":["80210","87396","80209","16172","2548"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-06-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"4600","bibliographicPageStart":"4590","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"Macromolecules"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"比江嶋, 祐介"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"新田, 晃平"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The influences of the polydispersity index (Mw/Mn) on the morphology and deformation behavior of high-density polyethylene solids under uniaxial stretching were investigated using in situ Raman spectroscopy. An increase in Mw/Mn led to a larger fraction of tie molecules connecting several lamellar crystals, whereas no obvious influence on the crystalline structures was observed. Although the stress-strain curves essentially remained unchanged up to the neck propagation region irrespective of Mw/Mn, the strain-hardening modulus was higher for higher Mw/Mn samples. These results indicate that the mechanical response of the network structure appears in the strain-hardening region because of the tie molecules connecting several lamellar crystals fragmented at the yield point. In addition, the molecular orientation of the crystalline chains into the stretching direction and the formation of long consecutive trans chains were enhanced for higher Mw/Mn samples. Copyright © 2019 American Chemical Society.","subitem_description_type":"Abstract"}]},"item_4_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Embargo Period 12 months","subitem_description_type":"Other"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域フロンティア工学系","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00055241","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.macromol.8b02740","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://pubs.acs.org/doi/10.1021/acs.macromol.8b02740"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acs.macromol.8b02740","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2019 American Chemical Society"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA0071963X","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0024-9297","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kida, Takumitsu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hiejima, Yusuke"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Nitta, Koh-Hei"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-27"}],"displaytype":"detail","filename":"TE-PR-HIEJIMA-Y-4590.pdf","filesize":[{"value":"5.5 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"TE-PR-HIEJIMA-Y-4590.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/48922/files/TE-PR-HIEJIMA-Y-4590.pdf"},"version_id":"0baa99df-6b8f-46f7-8888-b5b3196e8a9b"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Rheo-Raman Spectroscopic Study on Uniaxial Deformation Behavior of High-Density Polyethylene Solids with Various Molecular Weight Distributions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Rheo-Raman Spectroscopic Study on Uniaxial Deformation Behavior of High-Density Polyethylene Solids with Various Molecular Weight Distributions"}]},"item_type_id":"4","owner":"18","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-08-30"},"publish_date":"2019-08-30","publish_status":"0","recid":"48922","relation_version_is_last":true,"title":["Rheo-Raman Spectroscopic Study on Uniaxial Deformation Behavior of High-Density Polyethylene Solids with Various Molecular Weight Distributions"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T15:42:17.484262+00:00"}