{"created":"2023-07-27T06:54:49.756831+00:00","id":50360,"links":{},"metadata":{"_buckets":{"deposit":"9e088997-1a0c-484a-b236-24c72e5f6cf4"},"_deposit":{"created_by":18,"id":"50360","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50360"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050360","sets":["2812:2813:2815"]},"author_link":["91174","91173"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-06-11","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2017-04-01 - 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sakata, Yoko"}],"nameIdentifiers":[{"nameIdentifier":"91174","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70630630","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70630630"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本課題では、自己集合を利用した芳香環および金属錯体の壁で囲まれた空孔を持つベルト状環状金属錯体（メタロナノベルト）の構築を行った。屈曲型配位子としてテトラアミノトリプチセンを用い、金属イオンとの自己集合によりメタロナノベルトの効率的な構築を試みた結果、ピラーアレーン誘導体をテンプレートとして利用することで、五核メタロナノベルトが定量的に形成できることを見出した。また、テンプレートを除きゲストフリーの五核メタロナノベルトを単離することにも成功し、メタロナノベルトは自己集合型錯体であるにも関わらず環サイズ変換に対して比較的安定な構造体であることも明らかにした。","subitem_description_type":"Abstract"},{"subitem_description":"We constructed a new self-assembled belt-shaped metallomacrocycle, metllonanobelt, having a cavity surrounded by aromatic walls and metal complexes. It was found that the pentanuclear metallonanobelt was selectively formed by the complexation of metal ions and tetraaminotriptycene in the presence of pillararene derivative as a template. We also succeeded in the isolation of guest-free pentamer metallonanobelt by the removal of the template. Furthermore, the isolated metallonanobelt was found to be remarkably stable toward size-conversion.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:17K14459, 研究期間(年度):2017-04-01 - 2019-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「湾曲π共役面を持つ新規金属埋め込み型ナノチューブの構築」課題番号17K14459\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K14459/17K14459seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00056669","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学理工研究域物質化学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=70630630"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=70630630","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K14459/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K14459/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K14459/17K14459seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K14459/17K14459seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"酒田, 陽子"}],"nameIdentifiers":[{"nameIdentifier":"91173","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70630630","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70630630"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-05-18"}],"displaytype":"detail","filename":"SC-PR-SAKATA-Y-kaken 2019-4p.pdf","filesize":[{"value":"476.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-SAKATA-Y-kaken 2019-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50360/files/SC-PR-SAKATA-Y-kaken 2019-4p.pdf"},"version_id":"09c2d946-0ceb-44f2-9640-86d11bc6bad9"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"湾曲π共役面を持つ新規金属埋め込み型ナノチューブの構築","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"湾曲π共役面を持つ新規金属埋め込み型ナノチューブの構築"},{"subitem_title":"Construction of New Curved Pi-Conjugated Nanotube Containing Metal Ions","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-05-18"},"publish_date":"2020-05-18","publish_status":"0","recid":"50360","relation_version_is_last":true,"title":["湾曲π共役面を持つ新規金属埋め込み型ナノチューブの構築"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:30:11.355390+00:00"}