{"created":"2023-07-27T06:54:49.802631+00:00","id":50361,"links":{},"metadata":{"_buckets":{"deposit":"89368502-5243-40ef-aa18-90a3b97a2eac"},"_deposit":{"created_by":18,"id":"50361","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50361"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050361","sets":["2812:2813:2818"]},"author_link":["91174","91173"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-09-21","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2014-04-01 - 2016-03-31","bibliographic_titles":[{"bibliographic_title":"平成27(2015)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2015 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sakata, Yoko"}],"nameIdentifiers":[{"nameIdentifier":"91174","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70630630","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70630630"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では、生体色素分子ビリルビンの最小構成単位であるジピリノンを基盤とした、新しい光応答性分子ユニットの新規開発を行った。まずは、種々のジピリノン誘導体を合成し、その光化学的性質の追跡を行った結果、エトキシカルボニル基を導入したジピリノン誘導体が高い異性化率を示す事を明らかにした。さらにこの分子は、クロロホルム中とメタノール中において光照射後に得られる異性体の熱安定性が大きく異なることを見いだし、溶媒によって熱可逆的なT型と熱不可逆的なP型との間で切り替えができる新しい光応答性分子として振る舞うことを明らかにした。","subitem_description_type":"Abstract"},{"subitem_description":"This study aimed at construction of new photo-responsive molecule based on dipyrrinone, which is a scaffold of biological pigment, bilirubin. It was revealed that a newly synthesized dipyrrinone derivative bearing ethoxycarbonyl group at the pyrrolic position underwent high photoisomerization conversion. We also found that this molecule exhibited a solvent-dependent dual-mode photochromism between T- and P-types. While it underwent thermally reversible (T-type) photoresponsive reaction in chloroform, it became a thermally irreversible (P-type) system in methanol.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:26810050, 研究期間(年度):2014-04-01 - 2016-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「分子極性チューニングに基づく光応答性機能材料の創成」課題番号:26810050\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26810050/26810050seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00056670","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=70630630"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=70630630","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26810050/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26810050/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26810050/26810050seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26810050/26810050seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"酒田, 陽子"}],"nameIdentifiers":[{"nameIdentifier":"91173","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70630630","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70630630"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-27"}],"displaytype":"detail","filename":"SC-PR-SAKATA-Y-kaken 2016-5p.pdf","filesize":[{"value":"714.9 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-SAKATA-Y-kaken 2016-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50361/files/SC-PR-SAKATA-Y-kaken 2016-5p.pdf"},"version_id":"f9bc57a9-a1bf-4202-bac8-def1d8008697"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"分子極性チューニングに基づく光応答性機能材料の創成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"分子極性チューニングに基づく光応答性機能材料の創成"},{"subitem_title":"Development of Photoresponsive Functional Materials Based on Molecular Polarities Tuning","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2818"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-01-27"},"publish_date":"2020-01-27","publish_status":"0","recid":"50361","relation_version_is_last":true,"title":["分子極性チューニングに基づく光応答性機能材料の創成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:41:30.912413+00:00"}