{"created":"2023-07-27T06:54:49.893725+00:00","id":50363,"links":{},"metadata":{"_buckets":{"deposit":"84605f80-473f-440d-a042-807d309fb3cd"},"_deposit":{"created_by":18,"id":"50363","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50363"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050363","sets":["2812:2813:2816"]},"author_link":["91178","91179"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-26","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2016-04-01 - 2018-03-31","bibliographic_titles":[{"bibliographic_title":"平成29(2017)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2017 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kakuta, Takahiro"}],"nameIdentifiers":[{"nameIdentifier":"91179","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70746495","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70746495"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"ハイブリッドナノゲルを利用したセンサー材料の創出を目的に、分子レベルで有機成分と無機成分がハイブリッドした構造のＰＯＳＳを利用した。ＰＯＳＳは、ビチオフェンもしくはトリフェニルアミンで結合され、ナノゲルを形成した。ビチオフェン架橋のナノゲルは、シリカ粒子の大きさにより発光波長が変化した。また、トリフェニルアミンで架橋したナノゲルは、トランス脂肪酸とシス脂肪酸を認識し、発光波長が変化した。一方、フッ素誘導体を導入したフッ素化ナノゲルは、常磁性化合物との共存により、生理活性アミノ化合物を認識し、フッ素ＮＭＲ信号が変化した。開発したハイブリッドナノゲルは、光・磁気を利用した検知材料として期待される。","subitem_description_type":"Abstract"},{"subitem_description":"To develop novel sensing materials by using hybrid nano-gel, POSS which consists of eight organic substituents and alternate Si-O bonds to form cage structures with Si atoms as vertices, was used. Hybrid nano-gels were formed by cross-linking POSS units with bithiophene or triphenylamine. Nano-gel composed of bithiophene showed different fluorescent peaks depending on size of silica particles. Moreover, different emission behaviors of triphenylamine-bonded nano-gel were observed by comparing trans-fatty acid with cis-fatty acid. On the other hand, mixture of nano-gel induced fluorine derivatives and paramagnetic compounds detected bioactive amino compounds by changing signals of 19 fluorine NMR. From these results, our hybrid nano-gels shows its potential applications in various fields such as detectors by using photo- and magnetic- stimuli.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:16K17913, 研究期間(年度):2016-04-01 - 2018-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「有機-無機ハイブリッドゲルの創出と光・磁気機能材料への応用」課題番号16K17913\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K17913/16K17913seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00056672","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=70746495"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=70746495","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K17913/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K17913/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K17913/16K17913seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K17913/16K17913seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"角田, 貴洋"}],"nameIdentifiers":[{"nameIdentifier":"91178","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70746495","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70746495"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-27"}],"displaytype":"detail","filename":"SC-PR-KAKUTA-T-kaken 2018-5p.pdf","filesize":[{"value":"326.2 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-KAKUTA-T-kaken 2018-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50363/files/SC-PR-KAKUTA-T-kaken 2018-5p.pdf"},"version_id":"4adb5a3f-7ddc-4d43-8e4e-bad3b5dda1b6"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"有機-無機ハイブリッドゲルの創出と光・磁気機能材料への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"有機-無機ハイブリッドゲルの創出と光・磁気機能材料への応用"},{"subitem_title":"Development of Organic-Inorganic Hybrid Gel and Its Application to Photo- and Magnetic- Functional Materials","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2816"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-01-27"},"publish_date":"2020-01-27","publish_status":"0","recid":"50363","relation_version_is_last":true,"title":["有機-無機ハイブリッドゲルの創出と光・磁気機能材料への応用"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:34:59.749584+00:00"}