{"created":"2023-07-27T06:54:50.755456+00:00","id":50390,"links":{},"metadata":{"_buckets":{"deposit":"7a5f8464-b42c-4f35-9343-5d248ef8b5b4"},"_deposit":{"created_by":18,"id":"50390","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50390"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050390","sets":["2812:2813:2815"]},"author_link":["76422","76421"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-24","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2016-10-21 - 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"電子的チューニングのための置換基導入が容易で，かつ，π電子欠乏性であるトリアジンをリン配位子へと組み込むことで高活性な金属錯体触媒を開発することが本研究目的である．合成したトリアジニルホスフィン配位子を用い，種々金属触媒反応の検討を行った結果，特にトリス（トリアジニル）ホスフィン配位子を用いた際に活性向上が見られた．また，トリアジン環上の置換基変換によって，金属錯体触媒の反応性を調整可能であることを明らかとした．","subitem_description_type":"Abstract"},{"subitem_description":"The purpose of this research is to develop highly active metal catalysts ligated by phosphines that are incorporated with triazines, because the triazines are electron-deficient and introduction of substituents on the triazine-ring for electronic tuning is facile. As a result of examining various metal catalysis, reactivity of catalytic reactions especially using tris(triazinyl)phosphines was improved. In addition, it was clarified that the reactivity changes depending on substituents of the triazine ring.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:16K08161, 研究期間(年度):2016-10-21 - 2019-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「電子欠乏性ホスフィン配位子の開発と触媒反応への応用」課題番号16K08161\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08161/16K08161seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00056699","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80453835"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80453835","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K08161/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K08161/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08161/16K08161seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K08161/16K08161seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-05-18"}],"displaytype":"detail","filename":"PH-PR-KITAMURA-M-kaken 2019-4p.pdf","filesize":[{"value":"162.1 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-KITAMURA-M-kaken 2019-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50390/files/PH-PR-KITAMURA-M-kaken 2019-4p.pdf"},"version_id":"26ddf004-b077-48ed-ad01-544911daf53a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"電子欠乏性ホスフィン配位子の開発と触媒反応への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"電子欠乏性ホスフィン配位子の開発と触媒反応への応用"},{"subitem_title":"Development of electron-deficient phosphine ligands and their application to catalysis","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-05-18"},"publish_date":"2020-05-18","publish_status":"0","recid":"50390","relation_version_is_last":true,"title":["電子欠乏性ホスフィン配位子の開発と触媒反応への応用"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:32:15.849264+00:00"}