{"created":"2023-07-27T06:54:52.741495+00:00","id":50437,"links":{},"metadata":{"_buckets":{"deposit":"5f539e81-95f9-4b93-87d2-7822d6febd2e"},"_deposit":{"created_by":18,"id":"50437","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50437"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050437","sets":["2812:2813:2818"]},"author_link":["91275","91276"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-05-26","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2013-04-01 - 2016-03-31","bibliographic_titles":[{"bibliographic_title":"平成27(2015)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2015 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"多数の反応点を有する触媒中間体の機能開発について取り組んだ結果、今回は特に、隣接原子による求電子的活性化について進展があった。（１）求電子的な有機金属中間体であるFischer型カルベン錯体を経由する触媒反応の開発に取り組んだ。カルベン錯体前駆体として、中性で安定なシクロプロペンを用いたところ、シクロプロペンと有機金属試薬の反応によるアリル金属中間体の発生と、適切な求電子剤への連続的な負荷反応が進行することを見出した。（２）多核錯体触媒を用いるフラノンの合成に成功した。（３）異核金属アロイクラスターによる蟻酸を還元剤として用いる選択的なアルキン還元に成功した。","subitem_description_type":"Abstract"},{"subitem_description":"The present project for the development of multi-active sites in catalysis revealed the electrophilic activation by neighboring atoms for the activation of a reactive site. (1) The use of Fischer-type carbene complexes as electrophilic organometallic intermediates realized the tandem nucleophilic addition reaction. The use of stable cyclopropenes as carbene precursors provides a allylmetal intermediates via the reaction with organometallic reagents, followed by the tandem allylation reaction of appropriate electrophiles took place efficiently. (2) The multi-metallic catalysts achieved the asymmetric conjugate addition to give chiral furnaces bearing a quaternary stereogenic center. (3) The bimetallic cluster system showed unique chemo- and stereoselectivity in the reduction of alkynes using formic acid.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:25288019, 研究期間(年度):2013-04-01 - 2016-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「触媒反応における多点反応場協同作用の開拓」課題番号25288019\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25288019/25288019seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"東京理科大学 / 金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00056746","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=70454064"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=70454064","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25288019/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25288019/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25288019/25288019seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25288019/25288019seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-03"}],"displaytype":"detail","filename":"SC-PR-ENDO-K-kaken 2016-5p.pdf","filesize":[{"value":"275.6 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-ENDO-K-kaken 2016-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50437/files/SC-PR-ENDO-K-kaken 2016-5p.pdf"},"version_id":"6fc656f6-ee45-4903-afb6-88eda1c27646"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"触媒反応における多点反応場協同作用の開拓","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"触媒反応における多点反応場協同作用の開拓"},{"subitem_title":"Cooperative Effect of Multi-Active Sites in Catalytic Reactions","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2818"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-02-03"},"publish_date":"2020-02-03","publish_status":"0","recid":"50437","relation_version_is_last":true,"title":["触媒反応における多点反応場協同作用の開拓"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T10:50:22.626850+00:00"}