{"created":"2023-07-27T06:55:08.085503+00:00","id":50834,"links":{},"metadata":{"_buckets":{"deposit":"b06ec1ed-1c01-440f-9493-f1706ebb9c14"},"_deposit":{"created_by":18,"id":"50834","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50834"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050834","sets":["2812:2813:2823"]},"author_link":["388","92033"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-05-11","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"4p.","bibliographicVolumeNumber":"2008-2010","bibliographic_titles":[{"bibliographic_title":"平成22(2010)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2010 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Calix[4]areneとCalix[6]areneが交互に連結した交互共重合体の合成を行った。得られた高分子は、ゲスト分子としてFluorantheneを包接することが分かった。また、CDのゲスト部位であるデシル基とCucurbit[7]urilのゲスト部位であるビオロゲン基を側鎖に有する感温性ポリマーの合成を行った。α-CDまたはCB7を加えた場合、α-CD、CB7がポリマーの集合を阻害するためLCSTが上昇した。一方γ-CDを加えると、γ-CDとデシル基との1:2包接錯体が架橋剤の役割を果たし、ポリマーの集合が誘発されるためLCSTが下降した。","subitem_description_type":"Abstract"},{"subitem_description":"We synthesized a novel alternating copolymer composed of calix[4]arene and calix[6]arene. Compared to the model compounds of calix[4]arene and calix[6]arene, the alternating copolymer strongly captured fluoranthene because of multipoint host-guest interactions between the calixarenes in the alternating copolymer and fluoranthene. We also synthesized novel thermo-sensitive polymer carrying two stations of decyl and viologen moieties at the side chain. The polymer was prepared by radical copolymerization of N-isopropylacrylamide and styrene derivative having decyl and viologen moieties. The decyl and viologen moieties of the polymer formed host-guest complex with α-cyclodextrin and cucurbit[7]uril, respectively.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"出典：研究課題「交互ヘテロ環状ホスト高分子を基とした特異的反応場の創成」課題番号20550120\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20550120/20550120seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学自然科学研究科","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00057142","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=20019772"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=20019772","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20550120/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20550120/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20550120/20550120seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-20550120/20550120seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-28"}],"displaytype":"detail","filename":"SC-PR-NAKAMITO-T-kaken 2011-4p.pdf","filesize":[{"value":"242.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-NAKAMITO-T-kaken 2011-4p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50834/files/SC-PR-NAKAMITO-T-kaken 2011-4p.pdf"},"version_id":"42c782fd-dbff-4f5d-81cc-6464ecc853d7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"交互ヘテロ環状ホスト高分子を基とした特異的反応場の創成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"交互ヘテロ環状ホスト高分子を基とした特異的反応場の創成"},{"subitem_title":"Construction of Specific Reaction Media Using Alternating Polymer Consisting of Hetero-Macrocyclic Host Molecules","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2823"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-02-28"},"publish_date":"2020-02-28","publish_status":"0","recid":"50834","relation_version_is_last":true,"title":["交互ヘテロ環状ホスト高分子を基とした特異的反応場の創成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:22:19.193374+00:00"}