{"created":"2023-07-27T06:55:08.269432+00:00","id":50841,"links":{},"metadata":{"_buckets":{"deposit":"05a86c3c-5a9c-459b-9a44-504b6a5b5ae0"},"_deposit":{"created_by":18,"id":"50841","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"50841"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00050841","sets":["2812:2813:2822"]},"author_link":["216","92044"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2009-2011","bibliographic_titles":[{"bibliographic_title":"平成23(2011)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2011 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kitagaki, Shinji"}],"nameIdentifiers":[{"nameIdentifier":"92044","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20281818","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=20281818"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[2. 2]パラシクロファンの剛直性と高い熱及び化学的安定性を利用して、それを面不斉有機触媒並びに配位子の骨格に利用する研究を行った。本骨格に各種官能基を位置選択的に導入する方法を開発し、チオウレア官能基が二つ直結した水素結合供与触媒、スペーサーとしてベンゼン環を一つ導入した酸塩基複合型ホスフィン触媒、及びスペーサーを二つ導入したC2対称型ビスオキサゾリン配位子を合成し、各種不斉反応に用いてそれらが有効に働くことを実証した。","subitem_description_type":"Abstract"},{"subitem_description":"Some[ 2. 2] paracyclophane-based planar-chiral organocatalysts and ligands were synthesized and evaluated. Bisthiourea organocatalyst whose functionalities are directly connected with[ 2. 2] paracyclophane backbone, acid-base organocatalyst, in which phosphine unit is connected with a cyclopanol via a spacer benzene ring, and C_2-symmetric bis(oxazoline) ligand, both of whose functionalities are connected with[ 2. 2] paracyclophane via a spacer, were found to catalyze organic transformations with high enantiocontrol.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"出典：研究課題「[2. 2]パラシクロファン骨格を利用した反応場の創製」課題番号21590007\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21590007/21590007seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00057149","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学医薬保健研究域薬学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=20281818"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=20281818","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21590007/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21590007/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21590007/21590007seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21590007/21590007seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"北垣, 伸治"}],"nameIdentifiers":[{"nameIdentifier":"216","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20281818","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=20281818"},{"nameIdentifier":"20281818","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000020281818"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-28"}],"displaytype":"detail","filename":"TE-PR-KITAGAKI-S-kaken 2012-5p.pdf","filesize":[{"value":"234.2 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"TE-PR-KITAGAKI-S-kaken 2012-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/50841/files/TE-PR-KITAGAKI-S-kaken 2012-5p.pdf"},"version_id":"377fd9df-7a1b-4fe0-9e38-8258d0e64ce2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"[2. 2]パラシクロファン骨格を利用した反応場の創製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"[2. 2]パラシクロファン骨格を利用した反応場の創製"},{"subitem_title":"Development of [2.2]paracyclophane-based catalyst","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2822"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-02-28"},"publish_date":"2020-02-28","publish_status":"0","recid":"50841","relation_version_is_last":true,"title":["[2. 2]パラシクロファン骨格を利用した反応場の創製"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:59:58.215801+00:00"}