{"created":"2023-07-27T06:55:29.426817+00:00","id":51458,"links":{},"metadata":{"_buckets":{"deposit":"8f9b98c6-b74b-4773-8b2e-345685e05391"},"_deposit":{"created_by":18,"id":"51458","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"51458"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00051458","sets":["2812:2813:3929"]},"author_link":["50470","79246"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-07-13","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2016-04-01 - 2020-03-31","bibliographic_titles":[{"bibliographic_title":"令和1(2019)年度 科学研究費補助金 若手研究(B) 研究成果報告書"},{"bibliographic_title":"2019 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本課題では、固体NMRによる非晶性物質の構造解析を可能とするため、炭素１３原子間の距離情報の精度向上を目的として研究を行った。成果の概要は以下のようになる。（１）炭素間の交換速度の数式を導出し、直接結合している炭素間で３%以下の精度で原子間距離を求めた。（２）１つの炭素のみを標識したアミノ酸において、1２%以下の精度で炭素原子間距離が求められることを示した。","subitem_description_type":"Abstract"},{"subitem_description":"In this project, in order to enable the structural analysis of amorphous materials using solid-state NMR, methods for determination of distances between carbon atoms (C-C distance) have been investigated for the purpose of improving distance information. Summary of the results obtained in this project is shown in the following, (1) Analytical formula to calculate exchange rates between carbon-13 atoms in 2D exchange NMR, which is applied for the C-C distance determination, was derived. Using the formula, C-C distances could be obtained with an accuracy of 3 % or less of the corresponding distances obtained by X-ray diffraction (X-ray distance) in two carbon-13 atoms directly bonded to each other. (2) In Valine whose one carbon atom was labeled on carbon-13, the four C-C distances between a carboxy carbon and other carbons were obtained with an accuracy of 12 % or less of the corresponding X-ray distances.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:16K17850, 研究期間(年度):2016-04-01 - 2020-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「非晶質試料の構造解析のための固体NMRによる炭素間距離決定法の開発」研究成果報告書　課題番号16K17850\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K17850/16K17850seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"国立研究開発法人物質・材料研究機構 / 金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00057761","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=50533577"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=50533577","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K17850/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K17850/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K17850/16K17850seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-16K17850/16K17850seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-22"}],"displaytype":"detail","filename":"SC-PR-OHASHI-R-kaken 2020-6p.pdf","filesize":[{"value":"606.9 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-OHASHI-R-kaken 2020-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/51458/files/SC-PR-OHASHI-R-kaken 2020-6p.pdf"},"version_id":"5557ea96-3b45-4d9a-b95f-8c4d8de5b315"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"非晶質試料の構造解析のための固体NMRによる炭素間距離決定法の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"非晶質試料の構造解析のための固体NMRによる炭素間距離決定法の開発"},{"subitem_title":"Investigation of a method to determine distances between carbon atoms using solid-state NMR for structural analysis of amorphous samples","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["3929"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-04-22"},"publish_date":"2021-04-22","publish_status":"0","recid":"51458","relation_version_is_last":true,"title":["非晶質試料の構造解析のための固体NMRによる炭素間距離決定法の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T14:04:25.051073+00:00"}