{"created":"2023-07-27T06:55:29.932479+00:00","id":51470,"links":{},"metadata":{"_buckets":{"deposit":"2c595eef-a419-4d0f-9153-a564e8ddecc1"},"_deposit":{"created_by":18,"id":"51470","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"51470"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00051470","sets":["2812:2813:4014"]},"author_link":["3005","16527"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-05-27","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"11p.","bibliographicVolumeNumber":"2018-06-29 - 2021-03-31","bibliographic_titles":[{"bibliographic_title":"令和2(2020)年度 科学研究費補助金 挑戦的研究(萌芽) 研究成果報告書"},{"bibliographic_title":"2020 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"可視光を強く吸収する機能性材料を有機合成反応により直接改変することは、新材料の開発にあたり有力な手段である。一方、これらの材料を近年精力的に研究がなされている可視光を用いた有機合成反応へ適用することは、触媒の光吸収と競合するため困難である。本研究では、触媒のみが選択的に活性化される手段として近赤外光を用いた有機合成反応の検討を行った。結果、アザポルフィリン類を触媒としたトリフルオロメチル化反応や脱水素型カップリング反応の開発に成功した。さらに、これらの反応を可視光材料の改変に適用できることも示し、材料開発における新たな手段を提案できた。","subitem_description_type":"Abstract"},{"subitem_description":"In developing new materials, the direct conversion of materials that absorb visible light is a powerful strategy. On the other hand, it is difficult to apply visible-light-absorbing materials to visible-light mediated organic photoredox reactions, which has attracted much attention because the absorption of catalysts competes for substrates. In this study, we investigated the NIR-light mediated organic reactions toward a selective activation of catalysts. By using fine-tuned azaporphyrin-based photocatalyst, trifluoromethylation and dehydrogenative coupling reactions could be developed. Furthermore, these reactions can be applied to the direct conversion of visible light materials. Therefore, these NIR-mediated photoreactions are new tools for the development of novel materials.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:18K19071, 研究期間(年度):2018-06-29 - 2021-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「材料合成に革新をもたらす「近赤外フォトレドックス反応」の開発」研究成果報告書　課題番号18K19071\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-18K19071/18K19071seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00057773","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学理工研究域物質化学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=30584528"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=30584528","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K19071/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K19071/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-18K19071/18K19071seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-18K19071/18K19071seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-02-03"}],"displaytype":"detail","filename":"SC-PR-FURUYAMA-T-kaken 2021-11p.pdf","filesize":[{"value":"680.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-FURUYAMA-T-kaken 2021-11p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/51470/files/SC-PR-FURUYAMA-T-kaken 2021-11p.pdf"},"version_id":"d2a9ec06-3865-4918-8a05-9856eee40170"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"材料合成に革新をもたらす「近赤外フォトレドックス反応」の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"材料合成に革新をもたらす「近赤外フォトレドックス反応」の開発"},{"subitem_title":"Development of NIR-photoredox reactions for functionalization of organic materials","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["4014"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-02-03"},"publish_date":"2022-02-03","publish_status":"0","recid":"51470","relation_version_is_last":true,"title":["材料合成に革新をもたらす「近赤外フォトレドックス反応」の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:53:08.908199+00:00"}