{"created":"2023-07-27T06:55:33.267701+00:00","id":51588,"links":{},"metadata":{"_buckets":{"deposit":"5716157b-fb4f-4eba-b2e3-c3e8d7594143"},"_deposit":{"created_by":18,"id":"51588","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"51588"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00051588","sets":["2812:2813:3929"]},"author_link":["78865","2671"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-17","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"15p.","bibliographicVolumeNumber":"2017-04-01 - 2020-03-31","bibliographic_titles":[{"bibliographic_title":"令和1(2019)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2019 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Inagaki, Fuyuhiko"}],"nameIdentifiers":[{"nameIdentifier":"78865","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80506816","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=80506816"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"電子受容性のZ型配位子の隣接金属へ及ぼす反応への影響は未だ未開拓である。今回、新たな反応性創出を目的に、電子求引性基を持つ新規Z型配位子含有金属錯体を合成し、触媒反応に適用したところ、連続的7-exo型環化反応、カルボキシル化、分子内[4+2]型環化付加、7-endo-trig型環化反応等が進行することを見出した。","subitem_description_type":"Abstract"},{"subitem_description":"The effect of electron-accepting Z-type ligands on the reaction of adjacent metals is still unexplored. In this study, a new Z-type ligand-containing metal complex having an electron-withdrawing group was synthesized for the purpose of creating new reactivity and applied to a catalytic reaction .In conclusion, successive 7-exo cyclization, carboxylation, intramolecular [4 + 2] type cycloaddition, and 7-endo-trig type cycloaddition proceeded.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:17K08209, 研究期間(年度):2017-04-01 - 2020-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「電子求引性基を持つ新規Z型配位子含有金属錯体の合成とその触媒反応への応用」研究成果報告書　課題番号17K08209\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K08209/17K08209seika/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"神戸学院大学 / 金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00057891","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80506816"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80506816","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K08209/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K08209/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K08209/17K08209seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-17K08209/17K08209seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"稲垣, 冬彦"}],"nameIdentifiers":[{"nameIdentifier":"2671","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80506816","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=80506816"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-22"}],"displaytype":"detail","filename":"PH-PR-INAGAKI-F-kaken 2020-15p.pdf","filesize":[{"value":"334.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-INAGAKI-F-kaken 2020-15p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/51588/files/PH-PR-INAGAKI-F-kaken 2020-15p.pdf"},"version_id":"60a4e370-4ed5-489b-8828-acc9e3025796"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"電子求引性基を持つ新規Z型配位子含有金属錯体の合成とその触媒反応への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"電子求引性基を持つ新規Z型配位子含有金属錯体の合成とその触媒反応への応用"},{"subitem_title":"Synthesis of Z-type ligand-containing metal complex with electron-withdrawing group and its catalytic reaction","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["3929"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-04-22"},"publish_date":"2021-04-22","publish_status":"0","recid":"51588","relation_version_is_last":true,"title":["電子求引性基を持つ新規Z型配位子含有金属錯体の合成とその触媒反応への応用"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:25:00.306848+00:00"}