{"created":"2023-07-27T06:55:38.884969+00:00","id":51746,"links":{},"metadata":{"_buckets":{"deposit":"3602659d-501c-4f9b-a306-529867ea4d9e"},"_deposit":{"created_by":18,"id":"51746","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"51746"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00051746","sets":["2812:2813:4085"]},"author_link":["26926","1882"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-06-06","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"10p.","bibliographicVolumeNumber":"2019-04-01 - 2022-03-31","bibliographic_titles":[{"bibliographic_title":"令和3(2021)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2021 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Taniguchi, Tsuyoshi"}],"nameIdentifiers":[{"nameIdentifier":"26926","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60444204","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60444204"},{"nameIdentifier":"60444204","nameIdentifierScheme":"金沢大学研究者情報","nameIdentifierURI":"http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=60444204"},{"nameIdentifier":"60444204","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000060444204"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"As shown below, we developed new molecular transformation reactions using reactivity of nucleophilic boron-centered radicals (boryl radicals): (1) reactions ofβ-borylalkenyl radicals to inactive carbonyl groups; (2) reactions between boryl radicals and polyfluoroarenes; (3) synthesis of a strained benzoborepin and rearrangement; (4) trans-selective hydroboration of 1,3-diynes. These results were achieved by unique stereoelectronic effects and polar effects of radical intermediates that a boron atom induced.","subitem_description_type":"Abstract"},{"subitem_description":"求核的なホウ素中心ラジカル（ボリルラジカル）の反応性を利用して、以下の新しい分子変換反応を開発した。（１）β-ボリルアルケニルラジカルの不活性カルボニル基への反応、（２）ボリルラジカルとポリフルオロアレーンの反応、（３）歪んだベンゾボレピン誘導体の合成と転位反応、（４）１，３－ジイン誘導体のトランス選択的ヒドロホウ素化反応。これらの反応は、ホウ素原子によってもたらされたラジカル中間体の特異な立体電子効果および極性効果が発揮された結果、達成された。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:19K06972, 研究期間(年度):2019-04-01 - 2022-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「求核的ヘテロ原子中心ラジカルの特性を活用した高難度分子変換反応の開発」課題番号19K06972\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K06972/19K06972seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00058049","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=60444204"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=60444204","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K06972/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K06972/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K06972/19K06972seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K06972/19K06972seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"谷口, 剛史"}],"nameIdentifiers":[{"nameIdentifier":"1882","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60444204","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60444204"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-02-06"}],"displaytype":"detail","filename":"PH-PR-TANIGUCHI-T-kaken 2022-10p.pdf","filesize":[{"value":"501.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-TANIGUCHI-T-kaken 2022-10p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/51746/files/PH-PR-TANIGUCHI-T-kaken 2022-10p.pdf"},"version_id":"6b0b47ac-4978-413f-897c-544a8b86e142"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"求核的ヘテロ原子中心ラジカルの特性を活用した高難度分子変換反応の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"求核的ヘテロ原子中心ラジカルの特性を活用した高難度分子変換反応の開発"},{"subitem_title":"Development of challenging molecular transformation reactions using characters of nucleophilic heteroatom-centered radicals","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["4085"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-02-06"},"publish_date":"2023-02-06","publish_status":"0","recid":"51746","relation_version_is_last":true,"title":["求核的ヘテロ原子中心ラジカルの特性を活用した高難度分子変換反応の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:15:51.094448+00:00"}