{"created":"2023-07-27T06:55:40.518813+00:00","id":51809,"links":{},"metadata":{"_buckets":{"deposit":"32c49b02-658d-4818-a269-cb09fdff1939"},"_deposit":{"created_by":18,"id":"51809","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"51809"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00051809","sets":["2812:2813:4085"]},"author_link":["16172","2548"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-05-02","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"7p.","bibliographicVolumeNumber":"2018-04-01 - 2022-03-31","bibliographic_titles":[{"bibliographic_title":"令和3(2021)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2021 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hiejima, Yusuke"}],"nameIdentifiers":[{"nameIdentifier":"16172","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10415789","nameIdentifierScheme":"金沢大学研究者情報","nameIdentifierURI":"http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=10415789"},{"nameIdentifier":"10415789","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000010415789"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have succeeded to synthesize photoluminescent nanocarbon with red emission by using solvothermal method in ethanol. It is found that the photoluminescent nanocarbon is formed through the following mechanisms. Condensation polymerizations between o-phenylenediamine and catechol leads to polymeric precursor with green emission, followed by elimination of small molecules and formation of nanocarbon with red emission. Further reaction results in loss of red emission, where the nitrogen atoms are included into heterocyclic polyaromatics analogous to pyridine.","subitem_description_type":"Abstract"},{"subitem_description":"本研究では、エタノールを溶媒としたソルボサーマル合成によって、赤色発光を示す発光ナノカーボン合成に成功した。合成した発光ナノカーボンの分析から、o-フェニレンジアミンとカテコールが縮重合して、緑色発光を示す高分子状の前駆体を形成した後、赤色発光を示す直径5-10nm程度のナノ粒子を形成することがわかった。さらに反応が進行すると、赤色発光が徐々に失われるが、その際には、窒素原子周りで環化が進行してピリジン様の複素多環構造が形成される可能性がある。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:18K04808, 研究期間(年度):2018-04-01 - 2022-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「その場分光法を用いた発光ナノカーボンの生成機構の解明と連続合成法の開発」課題番号18K04808\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-18K04808/18K04808seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域フロンティア工学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00058112","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=10415789"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=10415789","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K04808/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K04808/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-18K04808/18K04808seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-18K04808/18K04808seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"比江嶋, 祐介"}],"nameIdentifiers":[{"nameIdentifier":"2548","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10415789","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=10415789"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-02-09"}],"displaytype":"detail","filename":"TE-PR-HIEJIMA-Y-kaken 2022-7p.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"TE-PR-HIEJIMA-Y-kaken 2022-7p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/51809/files/TE-PR-HIEJIMA-Y-kaken 2022-7p.pdf"},"version_id":"d6b30ce8-42ad-464f-a4c9-d7575791a970"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"その場分光法を用いた発光ナノカーボンの生成機構の解明と連続合成法の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"その場分光法を用いた発光ナノカーボンの生成機構の解明と連続合成法の開発"},{"subitem_title":"In situ spectroscopic observation of formation of photoluminescent nanocarbon and development of continuous synthesis","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["4085"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-02-09"},"publish_date":"2023-02-09","publish_status":"0","recid":"51809","relation_version_is_last":true,"title":["その場分光法を用いた発光ナノカーボンの生成機構の解明と連続合成法の開発"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:17:06.038379+00:00"}