{"created":"2023-07-27T06:56:05.504884+00:00","id":52697,"links":{},"metadata":{"_buckets":{"deposit":"0dafbd99-fa68-490d-921d-ebcfed3c7b63"},"_deposit":{"created_by":18,"id":"52697","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"52697"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00052697","sets":["2812:2813:4014"]},"author_link":["94347"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-06-08","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2019-08-30 – 2021-03-31","bibliographic_titles":[{"bibliographic_title":"令和2(2020)年度 科学研究費補助金 研究活動スタート支援 研究成果報告書"},{"bibliographic_title":"2020 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shigeta, Yasuhiro"}],"nameIdentifiers":[{"nameIdentifier":"94347","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70844025","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70844025"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究課題では、蒸気に応答して可逆的に色や発光色を変化させる性質、「ベイポクロミズム」に関して、これを多段階化させ、蒸気定量可能性を探索することを目的とした。多段階化には、化合物に対してある一種類のゲスト分子を異なる組成で含んだ複数の結晶構造を安定化する必要があり、本研究ではハロゲンを有する金属錯体について検討を行った。\nその結果、種々の有機溶媒蒸気に応答してベイポクロミズムを発現する金属錯体の創製に成功し、それぞれの結晶構造においてハロゲンが多様な相互作用様式を示していることが分かった。また、同一組成でありながら結晶構造のみ異なる、結晶多形を示す物質が創製できる可能性が示唆された。","subitem_description_type":"Abstract"},{"subitem_description":"In this work, we tried to investigate multi-step vapochromism, to explore possibility for quantitative analysis of vapor molecules. To achieve the multi-step vapochromism, we focused on halogen atom modification in metal complexes because halogen atoms have been known to interact with other atoms through various forms of interactions.\nAs the result, we found metal complex with halogenated ligand exhibited vapochromism and halogen atoms formed various interaction modes in their crystal structure. Moreover, we also found another metal complex exhibit polymorphism which forms different crystal structure with same molecular composition, maybe due to the halogen atom modification.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:19K23649, 研究期間(年度):2019-08-30 – 2021-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「ベイポクロミズムの多段階化に基づく蒸気定量可能性の探索」研究成果報告書　課題番号19K23649\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K23649/19K23649seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学ナノマテリアル研究所","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00058991","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=70844025"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=70844025","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19K23649/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19K23649/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K23649/19K23649seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K23649/19K23649seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"重田, 泰宏"}],"nameIdentifiers":[{"nameIdentifier":"94347","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70844025","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70844025"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-02-25"}],"displaytype":"detail","filename":"FR-PR-SHIGETA-Y-kaken 2021-5p.pdf","filesize":[{"value":"363.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"FR-PR-SHIGETA-Y-kaken 2021-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/52697/files/FR-PR-SHIGETA-Y-kaken 2021-5p.pdf"},"version_id":"c0b89d63-8ffa-4cdb-a7f6-9e5f7b401449"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"ベイポクロミズムの多段階化に基づく蒸気定量可能性の探索","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ベイポクロミズムの多段階化に基づく蒸気定量可能性の探索"},{"subitem_title":"Investigation for the possibility of quantitative analysis of vapor molecules based on multi-step vapochromism","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["4014"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-02-25"},"publish_date":"2022-02-25","publish_status":"0","recid":"52697","relation_version_is_last":true,"title":["ベイポクロミズムの多段階化に基づく蒸気定量可能性の探索"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:19:31.729525+00:00"}