{"created":"2023-07-27T06:56:07.599916+00:00","id":52777,"links":{},"metadata":{"_buckets":{"deposit":"2e95148b-90c1-4da6-a10c-22137a1cdde5"},"_deposit":{"created_by":18,"id":"52777","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"52777"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00052777","sets":["2812:2813:4014"]},"author_link":["94359","71007"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-06-04","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2019-04-01 – 2021-03-31","bibliographic_titles":[{"bibliographic_title":"令和2(2020)年度 科学研究費補助金 若手研究 研究成果報告書"},{"bibliographic_title":"2020 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hirose, Daisuke"}],"nameIdentifiers":[{"nameIdentifier":"71007","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60806686","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60806686"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"キラルセンシングは、生体に作用する医薬・農薬分野において不可欠な技術であるだけでなく、不斉の起源を明らかにするためのツールとしても有用である。今回、ラセン記憶特性を示すポリフェニルアセチレン誘導体をCDプローブとして用いることで、従来法では正確な評価が困難な固体状態でのキラル蒸気検出や、検出が困難な微量もしくは極低光学純度のキラル化合物のキラルセンシングに成功した。","subitem_description_type":"Abstract"},{"subitem_description":"Chiral sensing is an indispensable technology in pharmaceuticals and agrochemicals that act on living organisms, furthermore, a tool for clarifying the origin of chirality. In this study, by using a poly(phenylacetylene) derivative that exhibits helicity memory properties as a circular dichroism (CD) probe, we succeeded in observing chiral vapors that are difficult to evaluate accurately using conventional methods, and chiral compounds with tiny amounts or extremely low optical purity.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:19K15621, 研究期間(年度):2019-04-01 – 2021-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：「ラセン高分子の記憶操作技術に基づく高感度キラルセンシング」研究成果報告書　課題番号19K15621\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K15621/19K15621seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00059070","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=60806686"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=60806686","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19K15621/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19K15621/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K15621/19K15621seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-19K15621/19K15621seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"廣瀬, 大祐"}],"nameIdentifiers":[{"nameIdentifier":"94359","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60806686","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60806686"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-02-25"}],"displaytype":"detail","filename":"SC-PR-HIROSE-D-kaken 2021-6p.pdf","filesize":[{"value":"205.7 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-HIROSE-D-kaken 2021-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/52777/files/SC-PR-HIROSE-D-kaken 2021-6p.pdf"},"version_id":"6c7548dd-382d-4b70-a966-b610b0df66c2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"ラセン高分子の記憶操作技術に基づく高感度キラルセンシング","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ラセン高分子の記憶操作技術に基づく高感度キラルセンシング"},{"subitem_title":"Chiral sensing using helical polymer based on helicity memory","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["4014"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-02-25"},"publish_date":"2022-02-25","publish_status":"0","recid":"52777","relation_version_is_last":true,"title":["ラセン高分子の記憶操作技術に基づく高感度キラルセンシング"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:22:14.770851+00:00"}