{"created":"2023-07-27T06:56:29.448039+00:00","id":53324,"links":{},"metadata":{"_buckets":{"deposit":"5d38bdbf-6d7d-4f40-944e-c2a97a0f112a"},"_deposit":{"created_by":18,"id":"53324","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"53324"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00053324","sets":["2812:2813:2819"]},"author_link":["148"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-05-25","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2012-04-01 – 2015-03-31","bibliographic_titles":[{"bibliographic_title":"平成26(2014)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2014 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"集積型二重結合であるアレン及び関連π成分を基盤とする、新たな反応性の開拓並びに天然物の効率的合成法の確立を目的に研究を行い、以下の成果を得た。\n1)アレン―アルキン体を用いたdouble Pauson-Khand型反応の開発，2)アレン―ニトロン体を用いた1,3-双極子環化付加反応の開発，3)Kopsihainanine Aの不斉全合成，4)Indicanoneの不斉全合成，5)Scytoneminの炭素アナログ合成，6)Fusicoccane型三環性骨格の効率的構築法の開発.","subitem_description_type":"Abstract"},{"subitem_description":"The following six results based on allene chemistry were observed.\n1)Regioselective intramolecular [3+2] annulation of allene-nitrones, 2)Molybdenum-mediated intramolecular double Pauson-Khand type reaction of bis(allenyne), 3)Asymmetric total synthesis of (+)-kopsihainanine A, 4)First total synthesis of (+)-indicanone, 5)The synthesis of a carbon analogue of scytonemin based on the double Pauson-Khand type adduct, 6)Syntheses of 6-8-5 tricyclic ring systems by carbonylative [2+2+1] cycloaddition of bis(allene)s.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:24390003, 研究期間(年度):2012-04-01 – 2015-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「集積型二重結合を基軸とする環化反応と天然物合成」課題番号24390003\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-24390003/24390003seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00059608","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=70143914"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=70143914","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-24390003/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-24390003/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-24390003/24390003seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-24390003/24390003seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-26"}],"displaytype":"detail","filename":"PH-PR-MUKAI-C-kaken 2015-6p.pdf","filesize":[{"value":"329.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-MUKAI-C-kaken 2015-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/53324/files/PH-PR-MUKAI-C-kaken 2015-6p.pdf"},"version_id":"05884d34-0c40-47ea-a6ee-5d9a8f53c67c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"集積型二重結合を基軸とする環化反応と天然物合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"集積型二重結合を基軸とする環化反応と天然物合成"},{"subitem_title":"Novel reactions and total syntheses of natural products based on cumulated double bonds","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2819"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-10-26"},"publish_date":"2020-10-26","publish_status":"0","recid":"53324","relation_version_is_last":true,"title":["集積型二重結合を基軸とする環化反応と天然物合成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T10:40:52.038948+00:00"}