{"created":"2023-07-27T06:56:29.921817+00:00","id":53331,"links":{},"metadata":{"_buckets":{"deposit":"017a741b-d0f5-4312-b5ad-6ecec17204fe"},"_deposit":{"created_by":18,"id":"53331","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"53331"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00053331","sets":["2812:2813:2815"]},"author_link":["148"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-08","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2015-04-01 – 2019-03-31","bibliographic_titles":[{"bibliographic_title":"平成30(2018)年度 科学研究費補助金 基盤研究(A) 研究成果報告書"},{"bibliographic_title":"2018 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"集積型二重結合であるアレンの直交するπ成分の特徴を活かし、ロジウム触媒を用いた多重結合成分との環化反応による新規反応性構築を目的に検討を行った。その結果、アルキン-アレン-アルキン体等を用いることにより、酸化的環化、還元的脱離を経る複数の新規他段階反応が進行し、対応する多環式骨格を得る手法を見出した。特筆すべき点として、アルキンに隣接する環歪みのない不活性C-C結合の活性化を伴う環化が進行した。","subitem_description_type":"Abstract"},{"subitem_description":"Taking into account the feature of the orthogonal π component of allene, which is an integrated double bond, investigation was conducted for the purpose of constructing a new reactivity by a cyclization reaction with a multiple bond component using a rhodium catalyst. As a result, by using an alkyne-allene-alkyne compound etc., a plurality of new other steps progressing through oxidative cyclization and reductive elimination proceed, and a method for obtaining a corresponding polycyclic skeleton was found. It should be noted that cyclization proceeded with activation of the inactive C―C bond without ring strain adjacent to the alkyne.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:15H02490, 研究期間(年度):2015-04-01 – 2019-03-31","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00059615","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=70143914"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=70143914","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-15H02490/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-15H02490/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-15H02490/15H02490seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-15H02490/15H02490seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-19"}],"displaytype":"detail","filename":"PH-PR-MUKKAI-C-kaken 2019-6p.pdf","filesize":[{"value":"168.6 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-MUKKAI-C-kaken 2019-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/53331/files/PH-PR-MUKKAI-C-kaken 2019-6p.pdf"},"version_id":"de9f4ac6-2b4f-4e44-95a7-9dac65f29e21"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"不活性アルキル鎖のC-C結合開裂:新たなブレークスルーの創出","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"不活性アルキル鎖のC-C結合開裂:新たなブレークスルーの創出"},{"subitem_title":"C-C Bond Activation of Unactivated Alkyl Compound","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2815"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-10-19"},"publish_date":"2020-10-19","publish_status":"0","recid":"53331","relation_version_is_last":true,"title":["不活性アルキル鎖のC-C結合開裂:新たなブレークスルーの創出"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T15:30:38.799985+00:00"}