{"created":"2023-07-27T06:56:29.989236+00:00","id":53332,"links":{},"metadata":{"_buckets":{"deposit":"50c5a6c7-342c-4f5a-b841-70d3f31799b9"},"_deposit":{"created_by":18,"id":"53332","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"53332"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00053332","sets":["2812:2813:2822"]},"author_link":["148"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2009 – 2011","bibliographic_titles":[{"bibliographic_title":"平成23(2011)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2011 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"アレンの高い反応性を活用して、分子内に二つのアレン部位を有する鎖状化合物の環化反応やアレニルシクロプロパンとアルキンの分子内環化異性化反応等、ロジウム(I)触媒を用いる各種環化反応を開発した。また、2-アレニルアニリンのSN2'型閉環反応と続く[ 4+2]環化付加反応によるカルバゾール誘導体の簡便合成法を開発した。さらに、アレンを用いる環化反応を利用して3種の天然物の全合成を達成した。","subitem_description_type":"Abstract"},{"subitem_description":"The following new reactions have been developed based on the allene functionality : i) Rh(I)-catalyzed cycloisomerization of bisallenes, ii) Rh(I)-catalyzed intramolecular[ 5+2] cycloaddition reaction of alkyne-allenylcyclopropanes, iii) intramolecular SN2'-type ring-closing reaction of 2-allenylaniline derivatives. In addition, several natural product syntheses have been accomplished using allene-based cyclization.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:21590008, 研究期間(年度):2009 – 2011","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「アレンの特性を活用する新規有用反応の開発とその天然物合成への応用研究」課題番号21590008\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-21590008/21590008seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学医薬保健研究域薬学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00059616","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=70143914"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=70143914","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-21590008/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-21590008/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-21590008/21590008seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-21590008/21590008seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-23"}],"displaytype":"detail","filename":"PH-PR-MUKAI-C-kaken 2012-6p.pdf","filesize":[{"value":"310.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-MUKAI-C-kaken 2012-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/53332/files/PH-PR-MUKAI-C-kaken 2012-6p.pdf"},"version_id":"95ae3ef3-fc0d-4a6b-a1ff-8ef0d2e48bf0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"アレンの特性を活用する新規有用反応の開発とその天然物合成への応用研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アレンの特性を活用する新規有用反応の開発とその天然物合成への応用研究"},{"subitem_title":"Development of new reactions based on the allene functionality and its application to natural product synthesis","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2822"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-10-23"},"publish_date":"2020-10-23","publish_status":"0","recid":"53332","relation_version_is_last":true,"title":["アレンの特性を活用する新規有用反応の開発とその天然物合成への応用研究"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T13:25:37.964374+00:00"}