{"created":"2023-07-27T06:56:33.481548+00:00","id":53397,"links":{},"metadata":{"_buckets":{"deposit":"c82b3297-20c0-4f40-9f5e-36f3b7df72ab"},"_deposit":{"created_by":18,"id":"53397","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"53397"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00053397","sets":["2812:2813:4085"]},"author_link":["94729"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-06-08","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2020-04-01 – 2022-03-31","bibliographic_titles":[{"bibliographic_title":"令和3(2021)年度 科学研究費補助金 若手研究 研究成果報告書"},{"bibliographic_title":"2021 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kurihara, Takuya"}],"nameIdentifiers":[{"nameIdentifier":"94729","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50858272","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=50858272"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Metal-organic frameworks (MOFs) are promising solid materials for gas storage and separation, ion conductor, and so on, This work investigated the mechanism of formation of glassy-state MOFs. Solid-state nuclear magnetic resonance (NMR) spectroscopy revealed that MOFs with high glass formability shows high mobility of ligands arising from weakness of coordination bonds and flexibility of coordination structures. Hence, molecular dynamics of MOF ligands would be an important factor for the vitrification of MOFs.","subitem_description_type":"Abstract"},{"subitem_description":"本研究では、ガス分離・貯蔵やイオン伝導等の機能が注目される金属-有機構造体(MOF)のガラス状態がどのように形成されるのか、固体核磁気共鳴分光法(NMR)を用いて研究を行った。新たに合成した2種類のMOFのガラス化のしやすさの差異について、MOFを構成する配位子の分子運動に着目してその原因を解析した。その結果、MOFの配位構造の柔軟性に起因する配位子の運動性が高いほど、ガラス状態を形成しやすいことが明らかとなった。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:20K15298, 研究期間(年度):2020-04-01 – 2022-03-31","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「金属-有機構造体の融解メカニズムの固体NMRを用いた解明」課題番号20K15298\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-20K15298/20K15298seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00059680","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=50858272"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=50858272","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-20K15298"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-20K15298","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-20K15298/20K15298seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-20K15298/20K15298seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"栗原, 拓也"}],"nameIdentifiers":[{"nameIdentifier":"94729","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50858272","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=50858272"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-02-20"}],"displaytype":"detail","filename":"SC-PR-KURIHARA-T-kaken 2022-5p.pdf","filesize":[{"value":"447.7 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-KURIHARA-T-kaken 2022-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/53397/files/SC-PR-KURIHARA-T-kaken 2022-5p.pdf"},"version_id":"09e5aa48-c0a0-458c-a074-5e9adae30d30"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"金属-有機構造体の融解メカニズムの固体NMRを用いた解明","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"金属-有機構造体の融解メカニズムの固体NMRを用いた解明"},{"subitem_title":"Melting and vitrification of metal-organic frameworks studied by solid-state NMR","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["4085"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-02-20"},"publish_date":"2023-02-20","publish_status":"0","recid":"53397","relation_version_is_last":true,"title":["金属-有機構造体の融解メカニズムの固体NMRを用いた解明"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-07-01T05:15:40.407436+00:00"}