@article{oai:kanazawa-u.repo.nii.ac.jp:00054051, author = {菅, 拓也 and 宇梶, 裕 and Suga, Takuya and Takahashi , Yuuki and Ukaji, Yutaka}, issue = {24}, journal = {Advanced Synthesis & Catalysis (ASC)}, month = {Oct}, note = {A “one‐shot” cross coupling between benzyl alcohols and alkenyl halides has been established. A combination of low‐valent Ti‐mediated C−OH homolysis and the prominent chemistry of Ni‐based radical catalysis afforded the desired cross‐coupled product with good efficiency. The reaction proceeded regardless of the electronic property of benzyl alcohols, and Ar−B bond remained intact throughout the reaction. Alkenyl bromides with various substitution patterns were applicable to this reaction. Attempts for utilizing sterically demanding tri‐substituted alkenes indicated that the steric hinderance mainly inhibited the radical‐trapping by Ni species. This reaction can be a simple and efficient strategy for synthesizing densely substituted allylbenzene derivatives., 金沢大学理工学域物質科学系}, pages = {5622--5626}, title = {One‐Shot Radical Cross Coupling Between Benzyl Alcohols and Alkenyl Halides Using Ni/Ti/Mn System}, volume = {362}, year = {2020} }