{"created":"2023-07-27T06:57:28.577631+00:00","id":54686,"links":{},"metadata":{"_buckets":{"deposit":"3044962e-97e2-4241-9b47-fd06e36ce46e"},"_deposit":{"created_by":18,"id":"54686","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"54686"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00054686","sets":["2812:2813:2826"]},"author_link":["80000","2561"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-21","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"2p.","bibliographicVolumeNumber":"2006 – 2007","bibliographic_titles":[{"bibliographic_title":"平成19(2007)年度 科学研究費補助金 若手研究(B) 研究概要"},{"bibliographic_title":"2007 Research Project Summary","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では,生体系で酸素分子活性化反応を行う非ヘム金属タンパク質で観測,推定されている反応中間体(酸素活性種を含む遷移金属錯体)を,合目的に創製し,それらの精密機能制御を通してこれら金属タンパクの機能発現機構の解明を目指した.\n1)酸素活性種を含む銅錯体:三脚型四座配位子を用いて,配位子のメチル基の水酸化反応における反応中間体を単離し,X線結晶構造解析により構造を明らかにした.\n2)酸素活性種を含む鉄錯体:二核化配位子を含む二核鉄(II)錯体を用いて非ヘム二核鉄酵素の機能モデル研究を行った.二核鉄パーオキソ錯体の架橋基が安息香酸の場合は,酸素分子運搬体であるヘムエリスリンに類似した可逆的酸素化挙動を示し,架橋基がトリフェニル酢酸架橋の場合は,トルエンモノオキシゲナーゼに類似した配位子のフェニル基の水酸化反応を行うことを明らかにし,酸素分子との反応の精密機能制御に成功した.\n3)酸素活性種を含む銅錯体:6-メチルピリジル基をサイドアームに有する二核化配位子の二核銅錯体を用いて,配位子の芳香環のNIHシフトを伴う水酸化反応の反応中間体を観測することに初めて成功し,その中間体は(μ-η^2:η^2-peroxo)dicopper(II)種であることを明らかにした.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:18750044, 研究期間(年度):2006 – 2007","subitem_description_type":"Other"},{"subitem_description":"出典：「酸素活性種を含む金属錯体の合目的創製および精密機能制御」研究成果報告書　課題番号18750044\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-18750044/)を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00060962","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/search/?kw=40332663"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/search/?kw=40332663","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-18750044/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-18750044/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-11-18"}],"displaytype":"detail","filename":"SC-PR-FURUTACHI-H-kaken 2016-2p.pdf","filesize":[{"value":"134.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-FURUTACHI-H-kaken 2016-2p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/54686/files/SC-PR-FURUTACHI-H-kaken 2016-2p.pdf"},"version_id":"8461b22a-feca-447e-905f-fff716a052d0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"酸素活性種を含む金属錯体の合目的創製および精密機能制御","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"酸素活性種を含む金属錯体の合目的創製および精密機能制御"}]},"item_type_id":"9","owner":"18","path":["2826"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-11-18"},"publish_date":"2021-11-18","publish_status":"0","recid":"54686","relation_version_is_last":true,"title":["酸素活性種を含む金属錯体の合目的創製および精密機能制御"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T14:19:56.128058+00:00"}